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Main Authors: Zhang, Xin, Zhang, Shihao
Format: Preprint
Published: 2025
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Online Access:https://arxiv.org/abs/2509.00430
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author Zhang, Xin
Zhang, Shihao
author_facet Zhang, Xin
Zhang, Shihao
contents Altermagnets, a newly discovered class of materials, exhibit zero net magnetization while hosting spin-split electronic bands. However, monolayer altermagnets maintain degenerate band gaps at the high-symmetry X and Y points in the Brillouin zone, manifesting a paravalley phase characterized by unpolarized valley states. In this work, we demonstrate that spontaneously broken valley degeneracy can be achieved through interlayer sliding in engineered M$_2$A$_2$B and M$_2$AA$'$B bilayer altermagnets by first-principles calculations and minimal microscopic model. We propose a promising route to achieve antiferromagnetic half-metal driven by sliding and emergent ferrovalley phase without applied electric field, which is realized in the V$_2$SSeO engineered bilayer. Our calculations also reveal that Mo$_2$O$_2$O exhibits the largest valley splitting gap of ~0.31 eV, making it a promising candidate for valley-spin valve devices. Furthermore, band structure calculations on Mo$_2$AA$'$O materials demonstrate that increasing the difference in atomic number ($Δ$Z) between A and A$'$ site atoms effectively enhances valley polarization. This work establishes a novel platform for discovering and controlling ferrovalley states in altermagnetic systems.
format Preprint
id arxiv_https___arxiv_org_abs_2509_00430
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Sliding-induced ferrovalley polarization and possible antiferromagnetic half-metal in bilayer altermagnets
Zhang, Xin
Zhang, Shihao
Materials Science
Mesoscale and Nanoscale Physics
Altermagnets, a newly discovered class of materials, exhibit zero net magnetization while hosting spin-split electronic bands. However, monolayer altermagnets maintain degenerate band gaps at the high-symmetry X and Y points in the Brillouin zone, manifesting a paravalley phase characterized by unpolarized valley states. In this work, we demonstrate that spontaneously broken valley degeneracy can be achieved through interlayer sliding in engineered M$_2$A$_2$B and M$_2$AA$'$B bilayer altermagnets by first-principles calculations and minimal microscopic model. We propose a promising route to achieve antiferromagnetic half-metal driven by sliding and emergent ferrovalley phase without applied electric field, which is realized in the V$_2$SSeO engineered bilayer. Our calculations also reveal that Mo$_2$O$_2$O exhibits the largest valley splitting gap of ~0.31 eV, making it a promising candidate for valley-spin valve devices. Furthermore, band structure calculations on Mo$_2$AA$'$O materials demonstrate that increasing the difference in atomic number ($Δ$Z) between A and A$'$ site atoms effectively enhances valley polarization. This work establishes a novel platform for discovering and controlling ferrovalley states in altermagnetic systems.
title Sliding-induced ferrovalley polarization and possible antiferromagnetic half-metal in bilayer altermagnets
topic Materials Science
Mesoscale and Nanoscale Physics
url https://arxiv.org/abs/2509.00430