Laser-induced Coulomb explosion of the LiI molecule and of its dimer
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arXiv
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| Autores principales: | , , , , , |
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| Formato: | Preprint |
| Publicado: |
2025
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| _version_ | 1866917233072013312 |
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| author | Kristensen, Henrik H. Hansen, Emil Christensen, Jeppe K. Albrechtsen, Simon H. Jensen, Frank Stapelfeldt, Henrik |
| author_facet | Kristensen, Henrik H. Hansen, Emil Christensen, Jeppe K. Albrechtsen, Simon H. Jensen, Frank Stapelfeldt, Henrik |
| contents | A gas-phase sample consisting of lithium iodide, $\mathrm{LiI}$, molecules and their dimer $\mathrm{(LiI)}_2$, are Coulomb exploded by an intense 25 femtosecond laser pulse. In the case of $\mathrm{LiI}$, we focus on the double ionization that creates a pair of $\mathrm{Li}^+$ and $\mathrm{I}^+$ recoil ions. From the kinetic energy distribution of the $\mathrm{Li}^+$ ions, extracted using coincidence filtering, we determine the distribution of internuclear distances $P(R)$ via the ground state potential curve of $\mathrm{LiI}^{2+}$ obtained from an ab initio calculation that accounts for non-Coulombic effects. We find that the center of $P(R)$ is close to the expected internuclear separation based on the three vibrational states of $\mathrm{LiI}$ populated, whereas the width of $P(R)$ exceeds the theoretical value by $\sim$ 52 %. We discuss if fragmentation via excited $\mathrm{LiI}^{2+}$ potential curves affects the determination of $P(R)$. In the case of the dimer, $\mathrm{(LiI)}_2$, we observe kinetic energies and relative emission directions of $\mathrm{Li}^+$, $\mathrm{I}^+$, and $\mathrm{I}^{2+}$ recoil ions consistent with Coulomb explosion of the parallelogram-shaped dimer after removing up to six electrons by the laser pulse. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2509_06458 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | Laser-induced Coulomb explosion of the LiI molecule and of its dimer Kristensen, Henrik H. Hansen, Emil Christensen, Jeppe K. Albrechtsen, Simon H. Jensen, Frank Stapelfeldt, Henrik Atomic Physics Atomic and Molecular Clusters A gas-phase sample consisting of lithium iodide, $\mathrm{LiI}$, molecules and their dimer $\mathrm{(LiI)}_2$, are Coulomb exploded by an intense 25 femtosecond laser pulse. In the case of $\mathrm{LiI}$, we focus on the double ionization that creates a pair of $\mathrm{Li}^+$ and $\mathrm{I}^+$ recoil ions. From the kinetic energy distribution of the $\mathrm{Li}^+$ ions, extracted using coincidence filtering, we determine the distribution of internuclear distances $P(R)$ via the ground state potential curve of $\mathrm{LiI}^{2+}$ obtained from an ab initio calculation that accounts for non-Coulombic effects. We find that the center of $P(R)$ is close to the expected internuclear separation based on the three vibrational states of $\mathrm{LiI}$ populated, whereas the width of $P(R)$ exceeds the theoretical value by $\sim$ 52 %. We discuss if fragmentation via excited $\mathrm{LiI}^{2+}$ potential curves affects the determination of $P(R)$. In the case of the dimer, $\mathrm{(LiI)}_2$, we observe kinetic energies and relative emission directions of $\mathrm{Li}^+$, $\mathrm{I}^+$, and $\mathrm{I}^{2+}$ recoil ions consistent with Coulomb explosion of the parallelogram-shaped dimer after removing up to six electrons by the laser pulse. |
| title | Laser-induced Coulomb explosion of the LiI molecule and of its dimer |
| topic | Atomic Physics Atomic and Molecular Clusters |
| url | https://arxiv.org/abs/2509.06458 |