Quantization of the electromagnetic fields from single atomic or molecular radiators

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1. Verfasser: Raicu, Valerica
Format: Preprint
Veröffentlicht: 2025
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author Raicu, Valerica
author_facet Raicu, Valerica
contents A framework is introduced for expressing electromagnetic (EM) potentials and fields of single atomic or molecular emitters modeled as oscillating dipoles, which follows a recently proposed method for solving inhomogeneous wave equations for arbitrary, time-dependent distributions of charge. This framework is first used to evaluate the physical implications of simplifying assumptions made in the standard approach to quantization of the EM fields and the impact of such assumptions on the results of energy and momentum quantization. Then, the exact expressions for the EM potentials and fields, in relation to the oscillating (transition) dipoles properties, afforded by the present framework are used to quantize electromagnetic fields from single emitters and restore the agreement with the well-known classical dipole radiation pattern, while maintaining the quantum mechanical description of electromagnetic radiation in terms of the probability distribution of quantum modes. Contributions of the present analysis to the understanding of photon emission from excited atoms or molecules stimulated by light or vacuum field fluctuations are highlighted, and possible experimental tests and practical applications are proposed.
format Preprint
id arxiv_https___arxiv_org_abs_2509_07359
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Quantization of the electromagnetic fields from single atomic or molecular radiators
Raicu, Valerica
Quantum Physics
Classical Physics
Optics
A framework is introduced for expressing electromagnetic (EM) potentials and fields of single atomic or molecular emitters modeled as oscillating dipoles, which follows a recently proposed method for solving inhomogeneous wave equations for arbitrary, time-dependent distributions of charge. This framework is first used to evaluate the physical implications of simplifying assumptions made in the standard approach to quantization of the EM fields and the impact of such assumptions on the results of energy and momentum quantization. Then, the exact expressions for the EM potentials and fields, in relation to the oscillating (transition) dipoles properties, afforded by the present framework are used to quantize electromagnetic fields from single emitters and restore the agreement with the well-known classical dipole radiation pattern, while maintaining the quantum mechanical description of electromagnetic radiation in terms of the probability distribution of quantum modes. Contributions of the present analysis to the understanding of photon emission from excited atoms or molecules stimulated by light or vacuum field fluctuations are highlighted, and possible experimental tests and practical applications are proposed.
title Quantization of the electromagnetic fields from single atomic or molecular radiators
topic Quantum Physics
Classical Physics
Optics
url https://arxiv.org/abs/2509.07359