Exploring the magnetic landscape of easily-exfoliable two-dimensional materials

Fuente: arXiv
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Main Authors: Haddadi, Fatemeh, Campi, Davide, Santos, Flaviano dos, Mounet, Nicolas, Ponet, Louis, Marzari, Nicola, Gibertini, Marco
Format: Preprint
Published: 2025
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author Haddadi, Fatemeh
Campi, Davide
Santos, Flaviano dos
Mounet, Nicolas
Ponet, Louis
Marzari, Nicola
Gibertini, Marco
author_facet Haddadi, Fatemeh
Campi, Davide
Santos, Flaviano dos
Mounet, Nicolas
Ponet, Louis
Marzari, Nicola
Gibertini, Marco
contents Magnetic materials often exhibit complex energy landscapes with multiple local minima, each corresponding to a self-consistent electronic structure solution. Finding the global minimum is challenging, and heuristic methods are not always guaranteed to succeed. Here, we apply a recently developed automated workflow to systematically explore the energy landscape of 194 magnetic monolayers obtained from the Materials Cloud 2D crystals database and determine their ground-state magnetic order. Our approach enables effective control and sampling of orbital occupation matrices, allowing rapid identification of local minima. We find a diverse set of self-consistent collinear metastable states, further enriched by Hubbard-corrected energy functionals, when the $U$ parameters have been computed from first principles using linear-response theory. We categorise the monolayers by their magnetic ordering and highlight promising candidates. Our results include 109 ferromagnetic, 83 antiferromagnetic, and 2 altermagnetic monolayers, along with 12 novel ferromagnetic half-metals with potential for spintronics technologies.
format Preprint
id arxiv_https___arxiv_org_abs_2509_09531
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Exploring the magnetic landscape of easily-exfoliable two-dimensional materials
Haddadi, Fatemeh
Campi, Davide
Santos, Flaviano dos
Mounet, Nicolas
Ponet, Louis
Marzari, Nicola
Gibertini, Marco
Materials Science
Computational Physics
Magnetic materials often exhibit complex energy landscapes with multiple local minima, each corresponding to a self-consistent electronic structure solution. Finding the global minimum is challenging, and heuristic methods are not always guaranteed to succeed. Here, we apply a recently developed automated workflow to systematically explore the energy landscape of 194 magnetic monolayers obtained from the Materials Cloud 2D crystals database and determine their ground-state magnetic order. Our approach enables effective control and sampling of orbital occupation matrices, allowing rapid identification of local minima. We find a diverse set of self-consistent collinear metastable states, further enriched by Hubbard-corrected energy functionals, when the $U$ parameters have been computed from first principles using linear-response theory. We categorise the monolayers by their magnetic ordering and highlight promising candidates. Our results include 109 ferromagnetic, 83 antiferromagnetic, and 2 altermagnetic monolayers, along with 12 novel ferromagnetic half-metals with potential for spintronics technologies.
title Exploring the magnetic landscape of easily-exfoliable two-dimensional materials
topic Materials Science
Computational Physics
url https://arxiv.org/abs/2509.09531