Preparation of the First Cu-based Nb$_3$Sn Sample via Bronze Route for Quadrupole Resonator Testing

Fuente: arXiv
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Main Authors: Lu, Ming, Keckert, Sebastian, Kramer, Felix, Prudnikava, Alena, Knobloch, Jens, Zubtsovskii, Aleksandr, Kugeler, Oliver
Format: Preprint
Published: 2025
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author Lu, Ming
Keckert, Sebastian
Kramer, Felix
Prudnikava, Alena
Knobloch, Jens
Zubtsovskii, Aleksandr
Kugeler, Oliver
author_facet Lu, Ming
Keckert, Sebastian
Kramer, Felix
Prudnikava, Alena
Knobloch, Jens
Zubtsovskii, Aleksandr
Kugeler, Oliver
contents We report the first successful production of a Cu-based Nb$_3$Sn sample specifically designed for Quadrupole Resonator (QPR) testing, representing a significant step toward scalable RF superconducting coatings of Nb$_3$Sn on copper substrates. The sample was fabricated using an optimized electrochemical thermal synthesis (ETS) via the bronze route, incorporating several key advancements: electropolishing of the Cu substrate, electroplating of the bronze precursor layer, a tailored heat treatment at approximately 700 $^\circ$C to promote grain growth and suppress tin-rich impurity phases, and a newly developed chemical etching procedure for effective removal of surface bronze residues and contaminants. These improvements address longstanding challenges in the fabrication of high-quality Cu-based Nb$_3$Sn thin films. Subsequent QPR measurements yielded the peak magnetic field and temperature dependent surface resistance $R_s$, as well as the superconducting transition temperature and quench field. Although the achieved RF performance -- characterized by a minimum $R_s$ of 43.4 n$Ω$ at 4.5 K and 15 mT -- is not yet optimal, the results clearly demonstrate the feasibility of this approach and its potential for further enhancement through process refinement.
format Preprint
id arxiv_https___arxiv_org_abs_2509_11224
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Preparation of the First Cu-based Nb$_3$Sn Sample via Bronze Route for Quadrupole Resonator Testing
Lu, Ming
Keckert, Sebastian
Kramer, Felix
Prudnikava, Alena
Knobloch, Jens
Zubtsovskii, Aleksandr
Kugeler, Oliver
Applied Physics
We report the first successful production of a Cu-based Nb$_3$Sn sample specifically designed for Quadrupole Resonator (QPR) testing, representing a significant step toward scalable RF superconducting coatings of Nb$_3$Sn on copper substrates. The sample was fabricated using an optimized electrochemical thermal synthesis (ETS) via the bronze route, incorporating several key advancements: electropolishing of the Cu substrate, electroplating of the bronze precursor layer, a tailored heat treatment at approximately 700 $^\circ$C to promote grain growth and suppress tin-rich impurity phases, and a newly developed chemical etching procedure for effective removal of surface bronze residues and contaminants. These improvements address longstanding challenges in the fabrication of high-quality Cu-based Nb$_3$Sn thin films. Subsequent QPR measurements yielded the peak magnetic field and temperature dependent surface resistance $R_s$, as well as the superconducting transition temperature and quench field. Although the achieved RF performance -- characterized by a minimum $R_s$ of 43.4 n$Ω$ at 4.5 K and 15 mT -- is not yet optimal, the results clearly demonstrate the feasibility of this approach and its potential for further enhancement through process refinement.
title Preparation of the First Cu-based Nb$_3$Sn Sample via Bronze Route for Quadrupole Resonator Testing
topic Applied Physics
url https://arxiv.org/abs/2509.11224