Characterization of superconducting germanide and germanosilicide films of Pd, Pt, Rh and Ir formed by solid-phase epitaxy

Fuente: arXiv
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Autores principales: Li, Hao, Shang, Zhongxia, Lilly, Michael P., Myronov, Maksym, Rokhinson, Leonid P.
Formato: Preprint
Publicado: 2025
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author Li, Hao
Shang, Zhongxia
Lilly, Michael P.
Myronov, Maksym
Rokhinson, Leonid P.
author_facet Li, Hao
Shang, Zhongxia
Lilly, Michael P.
Myronov, Maksym
Rokhinson, Leonid P.
contents Facilitated by recent advances in strained Ge/SiGe quantum well (QW) growth technology, superconductor-semiconductor hybrid devices based on group IV materials have been developed, potentially augmenting the functionality of quantum circuits. The formation of highly transparent superconducting platinum germanosilicide (PtSiGe) contacts to Ge/SiGe heterostructures by solid-phase epitaxy between Pt and SiGe has recently been reported, although with a relatively low critical temperature $<1\,\mathrm{K}$. Here, we present a comparative study of the superconducting properties of Pt, Pd, Rh, and Ir germanides, along with an in-depth characterization of Ir(Si)Ge films formed by solid-phase epitaxy. For films fabricated under optimal epitaxy conditions, we report $T_\mathrm{c}=3.4\,\mathrm{K}$ ($2.6\,\mathrm{K}$ for IrGe (IrSiGe). High-resolution scanning transmission electron microscopy (HRSTEM) and energy-dispersive X-ray spectroscopy (EDX) reveal that Ir reacts with Ge substrates to form a polycrystalline IrGe layer with a sharp IrGe/Ge interface.
format Preprint
id arxiv_https___arxiv_org_abs_2509_14173
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Characterization of superconducting germanide and germanosilicide films of Pd, Pt, Rh and Ir formed by solid-phase epitaxy
Li, Hao
Shang, Zhongxia
Lilly, Michael P.
Myronov, Maksym
Rokhinson, Leonid P.
Superconductivity
Mesoscale and Nanoscale Physics
Materials Science
Facilitated by recent advances in strained Ge/SiGe quantum well (QW) growth technology, superconductor-semiconductor hybrid devices based on group IV materials have been developed, potentially augmenting the functionality of quantum circuits. The formation of highly transparent superconducting platinum germanosilicide (PtSiGe) contacts to Ge/SiGe heterostructures by solid-phase epitaxy between Pt and SiGe has recently been reported, although with a relatively low critical temperature $<1\,\mathrm{K}$. Here, we present a comparative study of the superconducting properties of Pt, Pd, Rh, and Ir germanides, along with an in-depth characterization of Ir(Si)Ge films formed by solid-phase epitaxy. For films fabricated under optimal epitaxy conditions, we report $T_\mathrm{c}=3.4\,\mathrm{K}$ ($2.6\,\mathrm{K}$ for IrGe (IrSiGe). High-resolution scanning transmission electron microscopy (HRSTEM) and energy-dispersive X-ray spectroscopy (EDX) reveal that Ir reacts with Ge substrates to form a polycrystalline IrGe layer with a sharp IrGe/Ge interface.
title Characterization of superconducting germanide and germanosilicide films of Pd, Pt, Rh and Ir formed by solid-phase epitaxy
topic Superconductivity
Mesoscale and Nanoscale Physics
Materials Science
url https://arxiv.org/abs/2509.14173