Saved in:
Bibliographic Details
Main Authors: Cioslowski, Jerzy, Strasburger, Krzysztof, Sunko, Denis K.
Format: Preprint
Published: 2025
Subjects:
Online Access:https://arxiv.org/abs/2509.17896
Tags: Add Tag
No Tags, Be the first to tag this record!
Table of Contents:
  • A rigorous characterization of the information content of any highest-spin three-fermion wave function is presented. It is based upon a formal decomposition of the wave function into a finite set of fixed invariants, called shapes, whose sole purpose is to satisfy the Pauli principle, and a variable part, constituting the bosonic excitations of these invariants, that provides its physical content. As an example, this decomposition is applied to a benchmark-quality approximate wave function of the lowest-energy quartet electronic state of the lithium atom. This wave function, which comprises hundreds of basis functions, is reduced to eleven shape blocks, only five of which are numerically significant. Such a compact characterization is a generic example of the appearance of superselection rules in configuration space, and provides a qualitative aid in the search for robust few-particle entangled states.