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Main Authors: Gómez-Torres, Hugo, Molina-Ruiz, Manel, Privitera, Simone, Menéndez, Enric, Abad, Llibertat, Sort, Jordi, Bourgeois, Olivier, Rodriguez-Viejo, Javier, Lopeandia, Aitor
Format: Preprint
Published: 2025
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Online Access:https://arxiv.org/abs/2509.18019
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author Gómez-Torres, Hugo
Molina-Ruiz, Manel
Privitera, Simone
Menéndez, Enric
Abad, Llibertat
Sort, Jordi
Bourgeois, Olivier
Rodriguez-Viejo, Javier
Lopeandia, Aitor
author_facet Gómez-Torres, Hugo
Molina-Ruiz, Manel
Privitera, Simone
Menéndez, Enric
Abad, Llibertat
Sort, Jordi
Bourgeois, Olivier
Rodriguez-Viejo, Javier
Lopeandia, Aitor
contents We introduce a nanocalorimetric technique based on microsecond-pulsed heating (μs-PHnC) that enables high-sensitivity, quasi-isothermal heat capacity measurements on nanoscale samples. Such resolution is critical for exploring thermodynamic signatures in low-dimensional materials, where conventional techniques fall short. By confining thermal excitation to microsecond timescales, this approach minimizes lateral heat diffusion, reduces heat capacity addenda to below 10^{-9} J K^{-1}, and achieves noise densities as low as 75 pJ K^{-1} Hz^{-1/2} mm^{-2}, unlocking precise thermodynamic characterization of subnanogram samples in areas as small as 30 x 30 μm^{2}. The method delivers exceptional temperature homogeneity, as demonstrated by resolving sharp phase transitions, such as the antiferromagnetic transition in ultrathin CoO films, with unprecedented clarity. Its quasi-static operation is inherently compatible with external stimuli, including magnetic and electric fields, thereby expanding its utility for in-operando thermodynamic studies. This advancement establishes a robust and scalable platform for probing thermal phenomena in nanostructured and low-dimensional materials, significantly broadening the scope of nanocalorimetry.
format Preprint
id arxiv_https___arxiv_org_abs_2509_18019
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Microsecond-Pulsed Nanocalorimetry: A Scalable Approach for Ultrasensitive Heat Capacity Measurements
Gómez-Torres, Hugo
Molina-Ruiz, Manel
Privitera, Simone
Menéndez, Enric
Abad, Llibertat
Sort, Jordi
Bourgeois, Olivier
Rodriguez-Viejo, Javier
Lopeandia, Aitor
Materials Science
Mesoscale and Nanoscale Physics
We introduce a nanocalorimetric technique based on microsecond-pulsed heating (μs-PHnC) that enables high-sensitivity, quasi-isothermal heat capacity measurements on nanoscale samples. Such resolution is critical for exploring thermodynamic signatures in low-dimensional materials, where conventional techniques fall short. By confining thermal excitation to microsecond timescales, this approach minimizes lateral heat diffusion, reduces heat capacity addenda to below 10^{-9} J K^{-1}, and achieves noise densities as low as 75 pJ K^{-1} Hz^{-1/2} mm^{-2}, unlocking precise thermodynamic characterization of subnanogram samples in areas as small as 30 x 30 μm^{2}. The method delivers exceptional temperature homogeneity, as demonstrated by resolving sharp phase transitions, such as the antiferromagnetic transition in ultrathin CoO films, with unprecedented clarity. Its quasi-static operation is inherently compatible with external stimuli, including magnetic and electric fields, thereby expanding its utility for in-operando thermodynamic studies. This advancement establishes a robust and scalable platform for probing thermal phenomena in nanostructured and low-dimensional materials, significantly broadening the scope of nanocalorimetry.
title Microsecond-Pulsed Nanocalorimetry: A Scalable Approach for Ultrasensitive Heat Capacity Measurements
topic Materials Science
Mesoscale and Nanoscale Physics
url https://arxiv.org/abs/2509.18019