Fast and compact time-resolved spectroscopy enabled by Quantum Walk Combs

Fuente: arXiv
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Main Authors: Heckelmann, Ina, Pinto, Davide, Schmitt, Uwe, Beck, Mattias, Faist, Jérôme
Format: Preprint
Published: 2025
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author Heckelmann, Ina
Pinto, Davide
Schmitt, Uwe
Beck, Mattias
Faist, Jérôme
author_facet Heckelmann, Ina
Pinto, Davide
Schmitt, Uwe
Beck, Mattias
Faist, Jérôme
contents Optical frequency combs paved the way for fast and compact multi-component optical chemical analysis due to their broadband spectra. Dual-comb spectrometers embody this technology, but their design requires a pair of matched combs, adding complexity to the system. In this study, we propose and implement a scheme for a rapid, compact spectroscopic analyser that operates without moving components, leveraging the tunability and speed of a single quantum walk comb laser. Previously, these combs have been shown to deliver stable, tunable and broadband lasing. Here, a single quantum cascade laser-based comb emitting within the significant molecular fingerprint region of the mid-infrared spectrum was employed in a non-interferometric setup for targeted and non-targeted analysis of various organic solvent vapours. With a time resolution as small as 10 microseconds and a high dynamic range reaching three orders of magnitude in concentration, this approach is suitable for the real-time analysis of chemical kinetics.
format Preprint
id arxiv_https___arxiv_org_abs_2509_20112
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Fast and compact time-resolved spectroscopy enabled by Quantum Walk Combs
Heckelmann, Ina
Pinto, Davide
Schmitt, Uwe
Beck, Mattias
Faist, Jérôme
Optics
Optical frequency combs paved the way for fast and compact multi-component optical chemical analysis due to their broadband spectra. Dual-comb spectrometers embody this technology, but their design requires a pair of matched combs, adding complexity to the system. In this study, we propose and implement a scheme for a rapid, compact spectroscopic analyser that operates without moving components, leveraging the tunability and speed of a single quantum walk comb laser. Previously, these combs have been shown to deliver stable, tunable and broadband lasing. Here, a single quantum cascade laser-based comb emitting within the significant molecular fingerprint region of the mid-infrared spectrum was employed in a non-interferometric setup for targeted and non-targeted analysis of various organic solvent vapours. With a time resolution as small as 10 microseconds and a high dynamic range reaching three orders of magnitude in concentration, this approach is suitable for the real-time analysis of chemical kinetics.
title Fast and compact time-resolved spectroscopy enabled by Quantum Walk Combs
topic Optics
url https://arxiv.org/abs/2509.20112