The Open-Source Photochem Code: A General Chemical and Climate Model for Interpreting (Exo)Planet Observations

Fuente: arXiv
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Autores principales: Wogan, Nicholas F., Batalha, Natasha E., Zahnle, Kevin, Krissansen-Totton, Joshua, Catling, David C., Wolf, Eric T., Robinson, Tyler D., Meadows, Victoria, Arney, Giada, Domagal-Goldman, Shawn
Formato: Preprint
Publicado: 2025
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author Wogan, Nicholas F.
Batalha, Natasha E.
Zahnle, Kevin
Krissansen-Totton, Joshua
Catling, David C.
Wolf, Eric T.
Robinson, Tyler D.
Meadows, Victoria
Arney, Giada
Domagal-Goldman, Shawn
author_facet Wogan, Nicholas F.
Batalha, Natasha E.
Zahnle, Kevin
Krissansen-Totton, Joshua
Catling, David C.
Wolf, Eric T.
Robinson, Tyler D.
Meadows, Victoria
Arney, Giada
Domagal-Goldman, Shawn
contents With the launch of the James Webb Space Telescope, we are firmly in the era of exoplanet atmosphere characterization. Understanding exoplanet spectra requires atmospheric chemical and climate models that span the diversity of planetary atmospheres. Here, we present a more general chemical and climate model of planetary atmospheres. Specifically, we introduce the open-source, one-dimensional photochemical and climate code Photochem, and benchmark the model against the observed compositions and climates of Venus, Earth, Mars, Jupiter and Titan with a single set of kinetics, thermodynamics and opacities. We also model the chemistry of the hot Jupiter exoplanet WASP-39b. All simulations are open-source and reproducible. To first order, Photochem broadly reproduces the gas-phase chemistry and pressure-temperature profiles of all six planets. The largest model-data discrepancies are found in Venus's sulfur chemistry, motivating future experimental work on sulfur kinetics and spacecraft missions to Venus. We also find that clouds and hazes are important for the energy balance of Venus, Earth, Mars and Titan, and that accurately predicting aerosols with Photochem is challenging. Finally, we benchmark Photochem against the popular VULCAN and HELIOS photochemistry and climate models, finding excellent agreement for the same inputs; we also find that Photochem simulates atmospheres 2 to 100 time more efficiently. These results show that Photochem provides a comparatively general description of atmospheric chemistry and physics that can be leveraged to study Solar System worlds or interpret telescope observations of exoplanets.
format Preprint
id arxiv_https___arxiv_org_abs_2509_25578
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle The Open-Source Photochem Code: A General Chemical and Climate Model for Interpreting (Exo)Planet Observations
Wogan, Nicholas F.
Batalha, Natasha E.
Zahnle, Kevin
Krissansen-Totton, Joshua
Catling, David C.
Wolf, Eric T.
Robinson, Tyler D.
Meadows, Victoria
Arney, Giada
Domagal-Goldman, Shawn
Earth and Planetary Astrophysics
Instrumentation and Methods for Astrophysics
With the launch of the James Webb Space Telescope, we are firmly in the era of exoplanet atmosphere characterization. Understanding exoplanet spectra requires atmospheric chemical and climate models that span the diversity of planetary atmospheres. Here, we present a more general chemical and climate model of planetary atmospheres. Specifically, we introduce the open-source, one-dimensional photochemical and climate code Photochem, and benchmark the model against the observed compositions and climates of Venus, Earth, Mars, Jupiter and Titan with a single set of kinetics, thermodynamics and opacities. We also model the chemistry of the hot Jupiter exoplanet WASP-39b. All simulations are open-source and reproducible. To first order, Photochem broadly reproduces the gas-phase chemistry and pressure-temperature profiles of all six planets. The largest model-data discrepancies are found in Venus's sulfur chemistry, motivating future experimental work on sulfur kinetics and spacecraft missions to Venus. We also find that clouds and hazes are important for the energy balance of Venus, Earth, Mars and Titan, and that accurately predicting aerosols with Photochem is challenging. Finally, we benchmark Photochem against the popular VULCAN and HELIOS photochemistry and climate models, finding excellent agreement for the same inputs; we also find that Photochem simulates atmospheres 2 to 100 time more efficiently. These results show that Photochem provides a comparatively general description of atmospheric chemistry and physics that can be leveraged to study Solar System worlds or interpret telescope observations of exoplanets.
title The Open-Source Photochem Code: A General Chemical and Climate Model for Interpreting (Exo)Planet Observations
topic Earth and Planetary Astrophysics
Instrumentation and Methods for Astrophysics
url https://arxiv.org/abs/2509.25578