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Hauptverfasser: Park, Junhyoung, Olivati, Andrea, Prato, Mirko, Kim, Min, Petrozza, Annamaria
Format: Preprint
Veröffentlicht: 2025
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Online-Zugang:https://arxiv.org/abs/2510.05564
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author Park, Junhyoung
Olivati, Andrea
Prato, Mirko
Kim, Min
Petrozza, Annamaria
author_facet Park, Junhyoung
Olivati, Andrea
Prato, Mirko
Kim, Min
Petrozza, Annamaria
contents Co-evaporation of formamidinium tin triiodide (FASnI3) precursors, without any additives or reducing agents, leads to the growth of a highly crystalline thin film which shows a bandgap around 1.31 eV, closely matching the theoretical value predicted from the ideal single crystal structure of FASnI3. The polycrystalline thin film presents a lower tendency of Sn2+ to Sn4+ oxidation and highly reduced tendency to self-doping, demonstrating, overall, an improved resistance to defects formation. These findings suggest solvent-free co-evaporation processes as a promising route for high quality Sn-based perovskite polycrystalline thin films.
format Preprint
id arxiv_https___arxiv_org_abs_2510_05564
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Co-evaporated Formamidinium tin triiodide with suppressed p-type self-doping
Park, Junhyoung
Olivati, Andrea
Prato, Mirko
Kim, Min
Petrozza, Annamaria
Materials Science
Chemical Physics
Co-evaporation of formamidinium tin triiodide (FASnI3) precursors, without any additives or reducing agents, leads to the growth of a highly crystalline thin film which shows a bandgap around 1.31 eV, closely matching the theoretical value predicted from the ideal single crystal structure of FASnI3. The polycrystalline thin film presents a lower tendency of Sn2+ to Sn4+ oxidation and highly reduced tendency to self-doping, demonstrating, overall, an improved resistance to defects formation. These findings suggest solvent-free co-evaporation processes as a promising route for high quality Sn-based perovskite polycrystalline thin films.
title Co-evaporated Formamidinium tin triiodide with suppressed p-type self-doping
topic Materials Science
Chemical Physics
url https://arxiv.org/abs/2510.05564