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| Main Authors: | , , , , , |
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| Format: | Preprint |
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2025
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| Subjects: | |
| Online Access: | https://arxiv.org/abs/2510.08897 |
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| _version_ | 1866908585657630720 |
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| author | Luo, Wei Deng, Sihan Xie, Muting Ji, Junyi Xiang, Hongjun Bellaiche, Laurent |
| author_facet | Luo, Wei Deng, Sihan Xie, Muting Ji, Junyi Xiang, Hongjun Bellaiche, Laurent |
| contents | Ferroelectricity is a cornerstone of functional materials research, enabling diverse technologies from non-volatile memory to optoelectronics. Recently, type-I integer quantum ferroelectricity (IQFE), unconstrained by symmetry, has been proposed and experimentally demonstrated; however, as it arises from ionic displacements of an integer lattice vector, the initial and final states are macroscopically indistinguishable, rendering the physical properties unchanged. Here, we propose for the first time the nontrivial counterpart (i.e., type-II IQFE) where the polarization difference between the initial and final states is quantized but the macroscopical properties differ. We further demonstrate the existence of type-II IQFE in bulk chiral tellurium. In few-layer tellurium, the total polarization remains nearly quantized, composed of a bulk-inherited quantum component and a small surface-induced contribution. Molecular dynamics simulations reveal surface-initiated, layer-by-layer switching driven by reduced energy barriers, explaining why ferroelectricity was observed experimentally in few-layer tellurium, but not in bulk tellurium yet. Interestingly, the chirality of the initial and final states in bulk tellurium is opposite, suggesting a novel way to control structural chirality with electric field in chiral photonics and nonvolatile ferroelectric memory devices. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2510_08897 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | Hidden integer quantum ferroelectricity in chiral Tellurium Luo, Wei Deng, Sihan Xie, Muting Ji, Junyi Xiang, Hongjun Bellaiche, Laurent Materials Science Ferroelectricity is a cornerstone of functional materials research, enabling diverse technologies from non-volatile memory to optoelectronics. Recently, type-I integer quantum ferroelectricity (IQFE), unconstrained by symmetry, has been proposed and experimentally demonstrated; however, as it arises from ionic displacements of an integer lattice vector, the initial and final states are macroscopically indistinguishable, rendering the physical properties unchanged. Here, we propose for the first time the nontrivial counterpart (i.e., type-II IQFE) where the polarization difference between the initial and final states is quantized but the macroscopical properties differ. We further demonstrate the existence of type-II IQFE in bulk chiral tellurium. In few-layer tellurium, the total polarization remains nearly quantized, composed of a bulk-inherited quantum component and a small surface-induced contribution. Molecular dynamics simulations reveal surface-initiated, layer-by-layer switching driven by reduced energy barriers, explaining why ferroelectricity was observed experimentally in few-layer tellurium, but not in bulk tellurium yet. Interestingly, the chirality of the initial and final states in bulk tellurium is opposite, suggesting a novel way to control structural chirality with electric field in chiral photonics and nonvolatile ferroelectric memory devices. |
| title | Hidden integer quantum ferroelectricity in chiral Tellurium |
| topic | Materials Science |
| url | https://arxiv.org/abs/2510.08897 |