Spinons, solitons and random singlets in the spin-chain compound copper benzoate

Fuente: arXiv
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Auteurs principaux: Chen, Ying, Duan, Guijing, Zhao, Yuejiu, Xi, Ning, Pan, Bingying, Xu, Xiaoyu, Wu, Zhanlong, Du, Kefan, Li, Shuo, Hu, Ze, Bian, Rui, Wang, Xiaoqun, Li, Wei, Zhang, Long, Cui, Yi, Li, Shiyan, Yu, Rong, Yu, Weiqiang
Format: Preprint
Publié: 2025
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author Chen, Ying
Duan, Guijing
Zhao, Yuejiu
Xi, Ning
Pan, Bingying
Xu, Xiaoyu
Wu, Zhanlong
Du, Kefan
Li, Shuo
Hu, Ze
Bian, Rui
Wang, Xiaoqun
Li, Wei
Zhang, Long
Cui, Yi
Li, Shiyan
Yu, Rong
Yu, Weiqiang
author_facet Chen, Ying
Duan, Guijing
Zhao, Yuejiu
Xi, Ning
Pan, Bingying
Xu, Xiaoyu
Wu, Zhanlong
Du, Kefan
Li, Shuo
Hu, Ze
Bian, Rui
Wang, Xiaoqun
Li, Wei
Zhang, Long
Cui, Yi
Li, Shiyan
Yu, Rong
Yu, Weiqiang
contents The $S=1/2$ antiferromagnetic Heisenberg chain is a paradigmatic quantum system hosting exotic excitations such as spinons and solitons, and forming random singlet state in the presence of quenched disorder. Realizing and distinguishing these excitations in a single material remains a significant challenge. Using nuclear magnetic resonance (NMR) on a high-quality single crystal of copper benzoate, we identify and characterize all three excitation types by tuning the magnetic field at ultra-low temperatures. At a low field of 0.2 T, a temperature-independent spin-lattice relaxation rate ($1/T_1$) over more than a decade confirms the presence of spinons. Below 0.4 K, an additional relaxation channel emerges, characterized by $1/T_1 \propto T$ and a spectral weight growing as $-\ln(T/T_0)$, signaling a random-singlet ground state induced by weak quenched disorder. At fields above 0.5 T, a field-induced spin gap $Δ\propto H^{2/3}$ observed in both $1/T_1$ and the Knight shift signifies soliton excitations. Our results establish copper benzoate as a unique experimental platform for studying one-dimensional quantum integrability and the interplay of disorder and correlations.
format Preprint
id arxiv_https___arxiv_org_abs_2510_11551
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Spinons, solitons and random singlets in the spin-chain compound copper benzoate
Chen, Ying
Duan, Guijing
Zhao, Yuejiu
Xi, Ning
Pan, Bingying
Xu, Xiaoyu
Wu, Zhanlong
Du, Kefan
Li, Shuo
Hu, Ze
Bian, Rui
Wang, Xiaoqun
Li, Wei
Zhang, Long
Cui, Yi
Li, Shiyan
Yu, Rong
Yu, Weiqiang
Strongly Correlated Electrons
The $S=1/2$ antiferromagnetic Heisenberg chain is a paradigmatic quantum system hosting exotic excitations such as spinons and solitons, and forming random singlet state in the presence of quenched disorder. Realizing and distinguishing these excitations in a single material remains a significant challenge. Using nuclear magnetic resonance (NMR) on a high-quality single crystal of copper benzoate, we identify and characterize all three excitation types by tuning the magnetic field at ultra-low temperatures. At a low field of 0.2 T, a temperature-independent spin-lattice relaxation rate ($1/T_1$) over more than a decade confirms the presence of spinons. Below 0.4 K, an additional relaxation channel emerges, characterized by $1/T_1 \propto T$ and a spectral weight growing as $-\ln(T/T_0)$, signaling a random-singlet ground state induced by weak quenched disorder. At fields above 0.5 T, a field-induced spin gap $Δ\propto H^{2/3}$ observed in both $1/T_1$ and the Knight shift signifies soliton excitations. Our results establish copper benzoate as a unique experimental platform for studying one-dimensional quantum integrability and the interplay of disorder and correlations.
title Spinons, solitons and random singlets in the spin-chain compound copper benzoate
topic Strongly Correlated Electrons
url https://arxiv.org/abs/2510.11551