Perturbation-assisted Observation of the Lowest Vibrational Level of the $\mathrm{b}^{3}Π_{0}$ State of Ultracold LiK Molecules
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2025
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| author | Yang, Anbang Nie, Xiaoyu Yu, Hao Lin Liu, Yiming Avalos, Victor He, Canming Klos, Jacek Kotochigova, Svetlana Dieckmann, Kai |
| author_facet | Yang, Anbang Nie, Xiaoyu Yu, Hao Lin Liu, Yiming Avalos, Victor He, Canming Klos, Jacek Kotochigova, Svetlana Dieckmann, Kai |
| contents | The narrow transition from the lowest rovibrational level of the $\mathrm{X}^{1}Σ^{+}$ electronic ground state to the lowest vibrational level of the $\mathrm{b}^{3}Π_{0}$ potential provides opportunities for achieving magic-wavelength trapping of ultracold bialkali molecules for enhancing their rotational coherence times. Guided by existing spectroscopic data of several perturbed and deeply-bound rovibrational states of the $\mathrm{A}^{1}Σ^{+}$ potential [Grochola et al., Chem. Phys. Lett., 2012, 535, 17-20], we conducted a targeted spectroscopic search and report the first observation of the lowest vibrational level of the $\mathrm{b}^{3}Π_{0}$ state in $^{6}\mathrm{Li}^{40}\mathrm{K}$. The transition frequency from $|\mathrm{X}^{1}Σ^{+},\,v=0,\,J=0>$ to $|\mathrm{b}^{3}Π_{0},\,v'=0,\,J'=1>$ is determined to be 314,230.5(5)GHz. Assisted by microwave spectroscopy, we resolved the rotational structure of $|\mathrm{b}^{3}Π_{0},\,v'=0>$ and extracted a rotational constant of $h\times8.576(44)$ GHz for the $\mathrm{b}^{3}Π_{0}$ state. From this, we deducted an energy separation between $|\mathrm{b}^{3}Π_{0},v'=0,J'=0>$ and $|\mathrm{X}^{1}Σ^{+},v=0,J=0>$ of $hc\times$10,481.03(2) $\mathrm{cm}^{-1}$. Our work provides timely and precise information on the deeply-bound region of the $\mathrm{b}^{3}Π_{0}$ triplet excited potential of LiK, and benefits future applications of ultracold LiK isotopologues in quantum simulation and quantum computation that demand long coherence times. |
| format | Preprint |
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arxiv_https___arxiv_org_abs_2510_17166 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | Perturbation-assisted Observation of the Lowest Vibrational Level of the $\mathrm{b}^{3}Π_{0}$ State of Ultracold LiK Molecules Yang, Anbang Nie, Xiaoyu Yu, Hao Lin Liu, Yiming Avalos, Victor He, Canming Klos, Jacek Kotochigova, Svetlana Dieckmann, Kai Atomic Physics Quantum Gases The narrow transition from the lowest rovibrational level of the $\mathrm{X}^{1}Σ^{+}$ electronic ground state to the lowest vibrational level of the $\mathrm{b}^{3}Π_{0}$ potential provides opportunities for achieving magic-wavelength trapping of ultracold bialkali molecules for enhancing their rotational coherence times. Guided by existing spectroscopic data of several perturbed and deeply-bound rovibrational states of the $\mathrm{A}^{1}Σ^{+}$ potential [Grochola et al., Chem. Phys. Lett., 2012, 535, 17-20], we conducted a targeted spectroscopic search and report the first observation of the lowest vibrational level of the $\mathrm{b}^{3}Π_{0}$ state in $^{6}\mathrm{Li}^{40}\mathrm{K}$. The transition frequency from $|\mathrm{X}^{1}Σ^{+},\,v=0,\,J=0>$ to $|\mathrm{b}^{3}Π_{0},\,v'=0,\,J'=1>$ is determined to be 314,230.5(5)GHz. Assisted by microwave spectroscopy, we resolved the rotational structure of $|\mathrm{b}^{3}Π_{0},\,v'=0>$ and extracted a rotational constant of $h\times8.576(44)$ GHz for the $\mathrm{b}^{3}Π_{0}$ state. From this, we deducted an energy separation between $|\mathrm{b}^{3}Π_{0},v'=0,J'=0>$ and $|\mathrm{X}^{1}Σ^{+},v=0,J=0>$ of $hc\times$10,481.03(2) $\mathrm{cm}^{-1}$. Our work provides timely and precise information on the deeply-bound region of the $\mathrm{b}^{3}Π_{0}$ triplet excited potential of LiK, and benefits future applications of ultracold LiK isotopologues in quantum simulation and quantum computation that demand long coherence times. |
| title | Perturbation-assisted Observation of the Lowest Vibrational Level of the $\mathrm{b}^{3}Π_{0}$ State of Ultracold LiK Molecules |
| topic | Atomic Physics Quantum Gases |
| url | https://arxiv.org/abs/2510.17166 |