SimplySQS: An Automated and Reproducible Workflow for Special Quasirandom Structure Generation with ATAT

Fuente: arXiv
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Autori principali: Lebeda, Miroslav, Drahokoupil, Jan, Vlčák, Petr, Svoboda, Šimon, van de Walle, Axel
Natura: Preprint
Pubblicazione: 2025
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author Lebeda, Miroslav
Drahokoupil, Jan
Vlčák, Petr
Svoboda, Šimon
van de Walle, Axel
author_facet Lebeda, Miroslav
Drahokoupil, Jan
Vlčák, Petr
Svoboda, Šimon
van de Walle, Axel
contents The special quasirandom structure (SQS) method is widely used for modeling disordered materials under periodic boundary conditions, with the ATAT mcsqs module being one of the most established implementations. However, SQS generation with mcsqs typically relies on manual preparation of input files, ad hoc execution scripts, and post-processing steps, which introduces user-dependent errors and limits reproducibility. Here, we present SimplySQS (https://simplysqs.com), an automated and reproducible workflow for SQS generation that is delivered through an online, interactive interface. SimplySQS guides users through structure import, compositional and supercell definition, and cluster parameter selection, while automatically generates all required ATAT input files and a single all-in-one execution script that encapsulates the complete search process. By standardizing input preparation, execution, and output analysis, the framework minimizes errors associated with manual file handling and enables consistent reproducibility of SQS searches. The workflow is demonstrated on the Pb1-xSrxTiO3 (PSTO, including PbTiO3 (PTO) and SrTiO3 (STO)) perovskite system. SQSs spanning the entire concentration range were generated using a single automated bash script produced by SimplySQS, after which all resulting structures were subjected to geometry optimization using a universal machine-learning interatomic potential (MACE MATPES-r2SCAN-0). This approach reliably reproduced the experimentally observed cubic-to-tetragonal transition near x = 0.5, with lattice parameters deviating by less than 1 % in the cubic region (x > 0.5) and less than 4 % in the tetragonal region (x < 0.5). Overall, SimplySQS transforms SQS generation with ATAT into intuitive, reproducible, and systematic framework for modeling disordered materials.
format Preprint
id arxiv_https___arxiv_org_abs_2510_18020
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle SimplySQS: An Automated and Reproducible Workflow for Special Quasirandom Structure Generation with ATAT
Lebeda, Miroslav
Drahokoupil, Jan
Vlčák, Petr
Svoboda, Šimon
van de Walle, Axel
Materials Science
The special quasirandom structure (SQS) method is widely used for modeling disordered materials under periodic boundary conditions, with the ATAT mcsqs module being one of the most established implementations. However, SQS generation with mcsqs typically relies on manual preparation of input files, ad hoc execution scripts, and post-processing steps, which introduces user-dependent errors and limits reproducibility. Here, we present SimplySQS (https://simplysqs.com), an automated and reproducible workflow for SQS generation that is delivered through an online, interactive interface. SimplySQS guides users through structure import, compositional and supercell definition, and cluster parameter selection, while automatically generates all required ATAT input files and a single all-in-one execution script that encapsulates the complete search process. By standardizing input preparation, execution, and output analysis, the framework minimizes errors associated with manual file handling and enables consistent reproducibility of SQS searches. The workflow is demonstrated on the Pb1-xSrxTiO3 (PSTO, including PbTiO3 (PTO) and SrTiO3 (STO)) perovskite system. SQSs spanning the entire concentration range were generated using a single automated bash script produced by SimplySQS, after which all resulting structures were subjected to geometry optimization using a universal machine-learning interatomic potential (MACE MATPES-r2SCAN-0). This approach reliably reproduced the experimentally observed cubic-to-tetragonal transition near x = 0.5, with lattice parameters deviating by less than 1 % in the cubic region (x > 0.5) and less than 4 % in the tetragonal region (x < 0.5). Overall, SimplySQS transforms SQS generation with ATAT into intuitive, reproducible, and systematic framework for modeling disordered materials.
title SimplySQS: An Automated and Reproducible Workflow for Special Quasirandom Structure Generation with ATAT
topic Materials Science
url https://arxiv.org/abs/2510.18020