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Autori principali: Das, Arpita, Tao, Albert Li, Fernley, Luke M., von Gierke, Fritz, Gregory, Philip D., Cornish, Simon L., Hutson, Jeremy M., Vexiau, Romain, Dulieu, Olivier
Natura: Preprint
Pubblicazione: 2025
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Accesso online:https://arxiv.org/abs/2510.24660
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author Das, Arpita
Tao, Albert Li
Fernley, Luke M.
von Gierke, Fritz
Gregory, Philip D.
Cornish, Simon L.
Hutson, Jeremy M.
Vexiau, Romain
Dulieu, Olivier
author_facet Das, Arpita
Tao, Albert Li
Fernley, Luke M.
von Gierke, Fritz
Gregory, Philip D.
Cornish, Simon L.
Hutson, Jeremy M.
Vexiau, Romain
Dulieu, Olivier
contents Using an ultracold gas of $^{87}$Rb$^{133}$Cs molecules, we perform hyperfine-resolved spectroscopy of transitions from the vibronic ground state to the lowest rovibrational states of the electronic state $\mathrm{b}\,^3Π_0$, as a function of magnetic field. These transitions are spin forbidden, resulting in narrow linewidths, and feature near-diagonal Franck-Condon factors. We develop a model of the hyperfine and Zeeman structure that includes coupling between the $0^+$ and $0^-$ components of $\mathrm{b}\,^3Π_0$. We fit the spectra to obtain rotational and hyperfine coupling constants. We measure transition dipole moments associated with specific transitions by directly observing Rabi oscillations as a function of a resonant laser pulse duration. Using resonant $π$ pulses, we prepare molecules in the electronically excited state and directly measure the spontaneous emission rate.
format Preprint
id arxiv_https___arxiv_org_abs_2510_24660
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Hyperfine-resolved optical spectroscopy of ultracold $^{87}$Rb$^{133}$Cs molecules: the $\mathrm{b}\,^3Π_0$ metastable state
Das, Arpita
Tao, Albert Li
Fernley, Luke M.
von Gierke, Fritz
Gregory, Philip D.
Cornish, Simon L.
Hutson, Jeremy M.
Vexiau, Romain
Dulieu, Olivier
Atomic Physics
Quantum Gases
Quantum Physics
Using an ultracold gas of $^{87}$Rb$^{133}$Cs molecules, we perform hyperfine-resolved spectroscopy of transitions from the vibronic ground state to the lowest rovibrational states of the electronic state $\mathrm{b}\,^3Π_0$, as a function of magnetic field. These transitions are spin forbidden, resulting in narrow linewidths, and feature near-diagonal Franck-Condon factors. We develop a model of the hyperfine and Zeeman structure that includes coupling between the $0^+$ and $0^-$ components of $\mathrm{b}\,^3Π_0$. We fit the spectra to obtain rotational and hyperfine coupling constants. We measure transition dipole moments associated with specific transitions by directly observing Rabi oscillations as a function of a resonant laser pulse duration. Using resonant $π$ pulses, we prepare molecules in the electronically excited state and directly measure the spontaneous emission rate.
title Hyperfine-resolved optical spectroscopy of ultracold $^{87}$Rb$^{133}$Cs molecules: the $\mathrm{b}\,^3Π_0$ metastable state
topic Atomic Physics
Quantum Gases
Quantum Physics
url https://arxiv.org/abs/2510.24660