The Fate of Hydrogen and Helium: From Planetary Embryos to Earth- and Neptune-like Worlds
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| Format: | Preprint |
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2025
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| _version_ | 1866915585093271552 |
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| author | Gupta, Akash Luo, Haiyang Deng, Jie Burrows, Adam |
| author_facet | Gupta, Akash Luo, Haiyang Deng, Jie Burrows, Adam |
| contents | Hydrogen, helium, silicates, and iron are key building blocks of rocky and gas-rich planets, yet their chemical interactions remain poorly constrained. Using first-principles molecular dynamics and thermodynamic integration, we quantify hydrogen and helium partitioning between molten silicate mantles and metallic cores for Earth-to-Neptune-mass planets. Hydrogen becomes strongly siderophilic above $\sim$25 GPa but weakens beyond $\sim$200 GPa, whereas helium remains lithophilic yet increasingly soluble in metal with pressure. Incorporating these trends into coupled structure-chemistry models suggests that majority of hydrogen and helium reside in planetary interiors, not atmospheres, with abundances strongly depending on planet mass. Such volatile exchange may influence the redox states of secondary atmospheres, longevity of primordial envelopes, predicted CHNOPS abundances, and emergence of helium-enriched atmospheres, while He 1083 nm and H Lyman-$α$ lines provide potential probes of atmosphere-interior exchange. These findings link atomic-scale interactions to planetary-scale observables, providing new constraints on the origins of Earth-to-Neptune-sized worlds. |
| format | Preprint |
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arxiv_https___arxiv_org_abs_2510_24956 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | The Fate of Hydrogen and Helium: From Planetary Embryos to Earth- and Neptune-like Worlds Gupta, Akash Luo, Haiyang Deng, Jie Burrows, Adam Earth and Planetary Astrophysics Materials Science Atmospheric and Oceanic Physics Computational Physics Hydrogen, helium, silicates, and iron are key building blocks of rocky and gas-rich planets, yet their chemical interactions remain poorly constrained. Using first-principles molecular dynamics and thermodynamic integration, we quantify hydrogen and helium partitioning between molten silicate mantles and metallic cores for Earth-to-Neptune-mass planets. Hydrogen becomes strongly siderophilic above $\sim$25 GPa but weakens beyond $\sim$200 GPa, whereas helium remains lithophilic yet increasingly soluble in metal with pressure. Incorporating these trends into coupled structure-chemistry models suggests that majority of hydrogen and helium reside in planetary interiors, not atmospheres, with abundances strongly depending on planet mass. Such volatile exchange may influence the redox states of secondary atmospheres, longevity of primordial envelopes, predicted CHNOPS abundances, and emergence of helium-enriched atmospheres, while He 1083 nm and H Lyman-$α$ lines provide potential probes of atmosphere-interior exchange. These findings link atomic-scale interactions to planetary-scale observables, providing new constraints on the origins of Earth-to-Neptune-sized worlds. |
| title | The Fate of Hydrogen and Helium: From Planetary Embryos to Earth- and Neptune-like Worlds |
| topic | Earth and Planetary Astrophysics Materials Science Atmospheric and Oceanic Physics Computational Physics |
| url | https://arxiv.org/abs/2510.24956 |