Engineering chlorine-based emitters in silicon carbide for telecom-band quantum technologies

Fuente: arXiv
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Main Authors: Anisimov, A. N., Mathews, A. V., Mavridou, K., Kentsch, U., Helm, M., Astakhov, G. V.
Format: Preprint
Published: 2025
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_version_ 1866912816620896256
author Anisimov, A. N.
Mathews, A. V.
Mavridou, K.
Kentsch, U.
Helm, M.
Astakhov, G. V.
author_facet Anisimov, A. N.
Mathews, A. V.
Mavridou, K.
Kentsch, U.
Helm, M.
Astakhov, G. V.
contents We report the experimental realization and optical characterization of chlorine-vacancy (ClV) color centers in 4H-SiC emitting in the fiber-optic telecom bands. These defects are created via chlorine ion implantation followed by high-temperature annealing. Photoluminescence spectroscopy reveals four distinct ClV configurations with zero-phonon lines (ZPLs) located in the O-band (1260 - 1360 nm), S-band (1460 - 1530 nm) and C-band (1530 - 1565 nm). Controlled implantation and annealing experiments confirm that the ClV centers originate specifically from chlorine incorporation into SiC and are not intrinsic to this material. We optimize the creation conditions for ClV ensembles and demonstrate negligible reduction of the ZPL intensity up to a temperature of 30 K. These results establish ClV defects as a new class of telecom-band color centers in a CMOS-compatible platform, offering strong potential for scalable quantum networks.
format Preprint
id arxiv_https___arxiv_org_abs_2510_25008
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Engineering chlorine-based emitters in silicon carbide for telecom-band quantum technologies
Anisimov, A. N.
Mathews, A. V.
Mavridou, K.
Kentsch, U.
Helm, M.
Astakhov, G. V.
Quantum Physics
We report the experimental realization and optical characterization of chlorine-vacancy (ClV) color centers in 4H-SiC emitting in the fiber-optic telecom bands. These defects are created via chlorine ion implantation followed by high-temperature annealing. Photoluminescence spectroscopy reveals four distinct ClV configurations with zero-phonon lines (ZPLs) located in the O-band (1260 - 1360 nm), S-band (1460 - 1530 nm) and C-band (1530 - 1565 nm). Controlled implantation and annealing experiments confirm that the ClV centers originate specifically from chlorine incorporation into SiC and are not intrinsic to this material. We optimize the creation conditions for ClV ensembles and demonstrate negligible reduction of the ZPL intensity up to a temperature of 30 K. These results establish ClV defects as a new class of telecom-band color centers in a CMOS-compatible platform, offering strong potential for scalable quantum networks.
title Engineering chlorine-based emitters in silicon carbide for telecom-band quantum technologies
topic Quantum Physics
url https://arxiv.org/abs/2510.25008