High-performance thermochromic multilayer coatings with W-doped VO2 nanoparticles dispersed in SiO2 matrix prepared on glass at a low temperature

Fuente: arXiv
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Main Authors: Vlcek, Jaroslav, Kaufman, Michal, Nia, Elnaz M., Houska, Jiri, Jiang, Jiechao, Cerstvy, Radomir, Haviar, Stanislav, Meletis, Efstathios I.
Format: Preprint
Published: 2025
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author Vlcek, Jaroslav
Kaufman, Michal
Nia, Elnaz M.
Houska, Jiri
Jiang, Jiechao
Cerstvy, Radomir
Haviar, Stanislav
Meletis, Efstathios I.
author_facet Vlcek, Jaroslav
Kaufman, Michal
Nia, Elnaz M.
Houska, Jiri
Jiang, Jiechao
Cerstvy, Radomir
Haviar, Stanislav
Meletis, Efstathios I.
contents We report a high-performance thermochromic VO2-based coating prepared by using a three-step process, consisting of magnetron sputter depositions of SiO2 films and V-W films and their postannealing, on standard glass at a low substrate temperature of 350 °C without opening the vacuum chamber to atmosphere. It is formed by four layers of W-doped VO2 nanoparticles dispersed in SiO2 matrix. The coating exhibits a transition temperature of 33 °C with an integral luminous transmittance of 65.4% (low-temperature state) and 60.1% (high-temperature state), and a modulation of the solar energy transmittance of 15.3%. Such a combination of properties, together with the low temperature during preparation, fulfill the requirements for large-scale implementation on building glass and have not been reported yet.
format Preprint
id arxiv_https___arxiv_org_abs_2510_27370
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle High-performance thermochromic multilayer coatings with W-doped VO2 nanoparticles dispersed in SiO2 matrix prepared on glass at a low temperature
Vlcek, Jaroslav
Kaufman, Michal
Nia, Elnaz M.
Houska, Jiri
Jiang, Jiechao
Cerstvy, Radomir
Haviar, Stanislav
Meletis, Efstathios I.
Materials Science
Applied Physics
We report a high-performance thermochromic VO2-based coating prepared by using a three-step process, consisting of magnetron sputter depositions of SiO2 films and V-W films and their postannealing, on standard glass at a low substrate temperature of 350 °C without opening the vacuum chamber to atmosphere. It is formed by four layers of W-doped VO2 nanoparticles dispersed in SiO2 matrix. The coating exhibits a transition temperature of 33 °C with an integral luminous transmittance of 65.4% (low-temperature state) and 60.1% (high-temperature state), and a modulation of the solar energy transmittance of 15.3%. Such a combination of properties, together with the low temperature during preparation, fulfill the requirements for large-scale implementation on building glass and have not been reported yet.
title High-performance thermochromic multilayer coatings with W-doped VO2 nanoparticles dispersed in SiO2 matrix prepared on glass at a low temperature
topic Materials Science
Applied Physics
url https://arxiv.org/abs/2510.27370