Systematic global structure search of bismuth-based binary systems under pressure using machine learning potentials

Fuente: arXiv
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Main Authors: Wakai, Hayato, Ishiwata, Shintaro, Seko, Atsuto
Format: Preprint
Published: 2025
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author Wakai, Hayato
Ishiwata, Shintaro
Seko, Atsuto
author_facet Wakai, Hayato
Ishiwata, Shintaro
Seko, Atsuto
contents Machine learning potentials (MLPs) have significantly advanced global crystal structure prediction by enabling efficient and accurate property evaluations. In this study, global structure searches are performed for 11 bismuth-based binary systems, including Na-Bi, Ca-Bi, and Eu-Bi, under pressures ranging from 0 to 20 GPa, employing polynomial MLPs developed specifically for these systems. The searches reveal numerous compounds not previously reported in the literature and identify all experimentally known compounds that are representable within the explored configurational space. These results highlight the robustness and reliability of the current MLP-based structure search. The study provides valuable insights into the discovery and design of novel bismuth-based materials under both ambient and high-pressure conditions.
format Preprint
id arxiv_https___arxiv_org_abs_2511_05188
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Systematic global structure search of bismuth-based binary systems under pressure using machine learning potentials
Wakai, Hayato
Ishiwata, Shintaro
Seko, Atsuto
Materials Science
Computational Physics
Machine learning potentials (MLPs) have significantly advanced global crystal structure prediction by enabling efficient and accurate property evaluations. In this study, global structure searches are performed for 11 bismuth-based binary systems, including Na-Bi, Ca-Bi, and Eu-Bi, under pressures ranging from 0 to 20 GPa, employing polynomial MLPs developed specifically for these systems. The searches reveal numerous compounds not previously reported in the literature and identify all experimentally known compounds that are representable within the explored configurational space. These results highlight the robustness and reliability of the current MLP-based structure search. The study provides valuable insights into the discovery and design of novel bismuth-based materials under both ambient and high-pressure conditions.
title Systematic global structure search of bismuth-based binary systems under pressure using machine learning potentials
topic Materials Science
Computational Physics
url https://arxiv.org/abs/2511.05188