Low-Temperature Heat Capacity and Phonon Dynamics in Expanded Graphite and EG--MWCNTs Composites
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2025
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| author | Krivchikov, A. I. Jeżowski, A. Barabashko, M. S. Dovbeshko, G. Hurova, D. E. Galtsov, N. N. Boiko, V. Sementsov, Yu. Glamazda, A. Sagan, V. Horbatenko, Yu. Korolyuk, O. A. Romantsova, O. O. Szewczyk, D. |
| author_facet | Krivchikov, A. I. Jeżowski, A. Barabashko, M. S. Dovbeshko, G. Hurova, D. E. Galtsov, N. N. Boiko, V. Sementsov, Yu. Glamazda, A. Sagan, V. Horbatenko, Yu. Korolyuk, O. A. Romantsova, O. O. Szewczyk, D. |
| contents | The specific heat of expanded graphite (EG) and EG--multiwalled carbon nanotube (MWCNT) composites (1.0 and 3.0 wt.\% MWCNTs) was measured between 2 and 300~K. The low-temperature heat capacity is dominated by out-of-plane flexural phonons with quadratic dispersion, characteristic of two-dimensional layered systems. Compared with crystalline graphite, EG exhibits enhanced heat capacity due to increased defect density and reduced interlayer coupling. Structural characterization (XRD, Raman, EDS) confirmed variations in stacking order and defect concentration. The data were fitted using a three-term model ($C_{1}T + C_{3}T^{3} + C_{5}T^{5}$), where the negative $C_{5}$ term indicates quadratic phonon dispersion. The results demonstrate the influence of MWCNT integration and structural disorder on phonon dynamics and anisotropic heat capacity in EG-based composites. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2511_09338 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | Low-Temperature Heat Capacity and Phonon Dynamics in Expanded Graphite and EG--MWCNTs Composites Krivchikov, A. I. Jeżowski, A. Barabashko, M. S. Dovbeshko, G. Hurova, D. E. Galtsov, N. N. Boiko, V. Sementsov, Yu. Glamazda, A. Sagan, V. Horbatenko, Yu. Korolyuk, O. A. Romantsova, O. O. Szewczyk, D. Materials Science The specific heat of expanded graphite (EG) and EG--multiwalled carbon nanotube (MWCNT) composites (1.0 and 3.0 wt.\% MWCNTs) was measured between 2 and 300~K. The low-temperature heat capacity is dominated by out-of-plane flexural phonons with quadratic dispersion, characteristic of two-dimensional layered systems. Compared with crystalline graphite, EG exhibits enhanced heat capacity due to increased defect density and reduced interlayer coupling. Structural characterization (XRD, Raman, EDS) confirmed variations in stacking order and defect concentration. The data were fitted using a three-term model ($C_{1}T + C_{3}T^{3} + C_{5}T^{5}$), where the negative $C_{5}$ term indicates quadratic phonon dispersion. The results demonstrate the influence of MWCNT integration and structural disorder on phonon dynamics and anisotropic heat capacity in EG-based composites. |
| title | Low-Temperature Heat Capacity and Phonon Dynamics in Expanded Graphite and EG--MWCNTs Composites |
| topic | Materials Science |
| url | https://arxiv.org/abs/2511.09338 |