A Brief Perspective on Piezotronic and Thermoelectric Coupling: Flexible Platforms for Synergistic Energy Scavenging and Peltier-Caloric Effects

Fuente: arXiv
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Autores principales: Carroll, David, Dun, ChaoChao
Formato: Preprint
Publicado: 2025
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author Carroll, David
Dun, ChaoChao
author_facet Carroll, David
Dun, ChaoChao
contents Advances in the development of flexible piezoelectric and thermoelectric materials have provided an important avenue for the exploration of energy scavenging through the thermodynamic-coupling of orthogonal energy-scavenging modalities. This has led to a body of work creating hybrid thermo/piezo-electric generator devices (T/PEGs) in which the two effects become thermodynamically entangled. Based on hetero- thin film architectures, such devices can exhibit a surprising power generation characteristic which is non-additive between the two energy-scavenging effects. For example, when the thermoelectric and piezoelectric effects are strongly coupled by their proximal fields, the efficacy of energy scavenging can be made to exceed that of the two effects independently. In this review of such effects, a basic coupled heat engine model is shown to provide insight into the origins of synergistic power generation. These models however, suggest the emergence of other combined thermodynamic properties such as the kinetic Peltier-Caloric Effect (PCE) traced to Onsager reciprocity. The recent observation of this effect in multicomponent systems is confirmation of the limited perspective of thermodynamic separability.
format Preprint
id arxiv_https___arxiv_org_abs_2511_09757
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle A Brief Perspective on Piezotronic and Thermoelectric Coupling: Flexible Platforms for Synergistic Energy Scavenging and Peltier-Caloric Effects
Carroll, David
Dun, ChaoChao
Materials Science
Mesoscale and Nanoscale Physics
Advances in the development of flexible piezoelectric and thermoelectric materials have provided an important avenue for the exploration of energy scavenging through the thermodynamic-coupling of orthogonal energy-scavenging modalities. This has led to a body of work creating hybrid thermo/piezo-electric generator devices (T/PEGs) in which the two effects become thermodynamically entangled. Based on hetero- thin film architectures, such devices can exhibit a surprising power generation characteristic which is non-additive between the two energy-scavenging effects. For example, when the thermoelectric and piezoelectric effects are strongly coupled by their proximal fields, the efficacy of energy scavenging can be made to exceed that of the two effects independently. In this review of such effects, a basic coupled heat engine model is shown to provide insight into the origins of synergistic power generation. These models however, suggest the emergence of other combined thermodynamic properties such as the kinetic Peltier-Caloric Effect (PCE) traced to Onsager reciprocity. The recent observation of this effect in multicomponent systems is confirmation of the limited perspective of thermodynamic separability.
title A Brief Perspective on Piezotronic and Thermoelectric Coupling: Flexible Platforms for Synergistic Energy Scavenging and Peltier-Caloric Effects
topic Materials Science
Mesoscale and Nanoscale Physics
url https://arxiv.org/abs/2511.09757