Response time of electrons to light in strong-field ionization of polar molecules

Fuente: arXiv
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Autori principali: Che, Jiayin, Ye, Sheng, Shen, Shiqi, Li, Weiyan, Chen, Yanjun
Natura: Preprint
Pubblicazione: 2025
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author Che, Jiayin
Ye, Sheng
Shen, Shiqi
Li, Weiyan
Chen, Yanjun
author_facet Che, Jiayin
Ye, Sheng
Shen, Shiqi
Li, Weiyan
Chen, Yanjun
contents We study tunneling ionization of HeH+ in strong elliptical laser fields numerically and analytically. The calculated photoelectron momentum distribution (PMD) show two different offset angles corresponding to ionization events occurring in the first and the second half cycles of one laser cycle. When the larger angle is greater than the angle of a model symmetric molecule with a similar ionization potential to the polar molecule, the smaller angle is smaller than the symmetric molecule. Using a developed strong-field model that consider effects of both the permanent dipole (PD) and the asymmetric Coulomb potential, we are able to quantitatively reproduce these phenomena. We show that the PD effect can increase (decrease) the response time of electrons within polar molecules to light in photoemission, thereby increasing (decreasing) the offset angle related to the first (second) half cycle of a laser cycle. The laser-dressed asymmetric Coulomb potential near the atomic nuclei also plays an important role in the sub-cycle-related response time and offset angle. This model may be useful for quantitatively studying attosecond ionization dynamics of polar molecules in strong laser fields.
format Preprint
id arxiv_https___arxiv_org_abs_2511_12087
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Response time of electrons to light in strong-field ionization of polar molecules
Che, Jiayin
Ye, Sheng
Shen, Shiqi
Li, Weiyan
Chen, Yanjun
Atomic Physics
We study tunneling ionization of HeH+ in strong elliptical laser fields numerically and analytically. The calculated photoelectron momentum distribution (PMD) show two different offset angles corresponding to ionization events occurring in the first and the second half cycles of one laser cycle. When the larger angle is greater than the angle of a model symmetric molecule with a similar ionization potential to the polar molecule, the smaller angle is smaller than the symmetric molecule. Using a developed strong-field model that consider effects of both the permanent dipole (PD) and the asymmetric Coulomb potential, we are able to quantitatively reproduce these phenomena. We show that the PD effect can increase (decrease) the response time of electrons within polar molecules to light in photoemission, thereby increasing (decreasing) the offset angle related to the first (second) half cycle of a laser cycle. The laser-dressed asymmetric Coulomb potential near the atomic nuclei also plays an important role in the sub-cycle-related response time and offset angle. This model may be useful for quantitatively studying attosecond ionization dynamics of polar molecules in strong laser fields.
title Response time of electrons to light in strong-field ionization of polar molecules
topic Atomic Physics
url https://arxiv.org/abs/2511.12087