Uncertainty-aware Physics-informed Neural Networks for Robust CARS-to-Raman Signal Reconstruction

Fuente: arXiv
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Autores principales: Venkataramanan, Aishwarya, Vemuri, Sai Karthikeya, Valapil, Adithya Ashok Chalain, Denzler, Joachim
Formato: Preprint
Publicado: 2025
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author Venkataramanan, Aishwarya
Vemuri, Sai Karthikeya
Valapil, Adithya Ashok Chalain
Denzler, Joachim
author_facet Venkataramanan, Aishwarya
Vemuri, Sai Karthikeya
Valapil, Adithya Ashok Chalain
Denzler, Joachim
contents Coherent anti-Stokes Raman scattering (CARS) spectroscopy is a powerful and rapid technique widely used in medicine, material science, and chemical analyses. However, its effectiveness is hindered by the presence of a non-resonant background that interferes with and distorts the true Raman signal. Deep learning methods have been employed to reconstruct the true Raman spectrum from measured CARS data using labeled datasets. A more recent development integrates the domain knowledge of Kramers-Kronig relationships and smoothness constraints in the form of physics-informed loss functions. However, these deterministic models lack the ability to quantify uncertainty, an essential feature for reliable deployment in high-stakes scientific and biomedical applications. In this work, we evaluate and compare various uncertainty quantification (UQ) techniques within the context of CARS-to-Raman signal reconstruction. Furthermore, we demonstrate that incorporating physics-informed constraints into these models improves their calibration, offering a promising path toward more trustworthy CARS data analysis.
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institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Uncertainty-aware Physics-informed Neural Networks for Robust CARS-to-Raman Signal Reconstruction
Venkataramanan, Aishwarya
Vemuri, Sai Karthikeya
Valapil, Adithya Ashok Chalain
Denzler, Joachim
Machine Learning
Coherent anti-Stokes Raman scattering (CARS) spectroscopy is a powerful and rapid technique widely used in medicine, material science, and chemical analyses. However, its effectiveness is hindered by the presence of a non-resonant background that interferes with and distorts the true Raman signal. Deep learning methods have been employed to reconstruct the true Raman spectrum from measured CARS data using labeled datasets. A more recent development integrates the domain knowledge of Kramers-Kronig relationships and smoothness constraints in the form of physics-informed loss functions. However, these deterministic models lack the ability to quantify uncertainty, an essential feature for reliable deployment in high-stakes scientific and biomedical applications. In this work, we evaluate and compare various uncertainty quantification (UQ) techniques within the context of CARS-to-Raman signal reconstruction. Furthermore, we demonstrate that incorporating physics-informed constraints into these models improves their calibration, offering a promising path toward more trustworthy CARS data analysis.
title Uncertainty-aware Physics-informed Neural Networks for Robust CARS-to-Raman Signal Reconstruction
topic Machine Learning
url https://arxiv.org/abs/2511.13185