Pressure-induced superconductivity in LaP2 with graphenelike phosphorus layer
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arXiv
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| Main Authors: | , , , , , |
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| Format: | Preprint |
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2025
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| _version_ | 1866914161287495680 |
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| author | Zhang, Mingxin Pei, Cuiying Zhu, Bangshuai Wang, Qi Wu, Juefei Qi, Yanpeng |
| author_facet | Zhang, Mingxin Pei, Cuiying Zhu, Bangshuai Wang, Qi Wu, Juefei Qi, Yanpeng |
| contents | Materials with graphene-like layers attract tremendous attention due to their electronic structures and superconducting properties. In this study, we synthesized LaP2 polycrystalline and observed a superconducting transition around 30 GPa. The critical temperature Tc increases monotonically with pressure, which is nearing saturation and reaches 7.8 K at 78 GPa. The synchrotron X-ray diffraction experiments confirm the superconducting transition originates from a structure transition to the P6/mmm phase under high pressure, suggesting the observation of graphene-like phosphorus layers in transition metal phosphides. By first-principles calculations, we provide more evidence for the stability of the graphene-like phosphorus layers in LaP2. Our findings are helpful for the understanding of the LaP2 phase diagram under high pressure, and could shed light on the research of unique structures in transition metal phosphides under high pressure. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2511_13405 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | Pressure-induced superconductivity in LaP2 with graphenelike phosphorus layer Zhang, Mingxin Pei, Cuiying Zhu, Bangshuai Wang, Qi Wu, Juefei Qi, Yanpeng Superconductivity Materials Science Materials with graphene-like layers attract tremendous attention due to their electronic structures and superconducting properties. In this study, we synthesized LaP2 polycrystalline and observed a superconducting transition around 30 GPa. The critical temperature Tc increases monotonically with pressure, which is nearing saturation and reaches 7.8 K at 78 GPa. The synchrotron X-ray diffraction experiments confirm the superconducting transition originates from a structure transition to the P6/mmm phase under high pressure, suggesting the observation of graphene-like phosphorus layers in transition metal phosphides. By first-principles calculations, we provide more evidence for the stability of the graphene-like phosphorus layers in LaP2. Our findings are helpful for the understanding of the LaP2 phase diagram under high pressure, and could shed light on the research of unique structures in transition metal phosphides under high pressure. |
| title | Pressure-induced superconductivity in LaP2 with graphenelike phosphorus layer |
| topic | Superconductivity Materials Science |
| url | https://arxiv.org/abs/2511.13405 |