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Main Authors: Grasdijk, Olivier, Kastelic, Jakob, Li, Jianhui, Timgren, Oskari, Wenz, Konrad, Yang, Yuanhang, Zhou, Perry, Kawall, David, Zelevinsky, Tanya, DeMille, David
Format: Preprint
Published: 2025
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Online Access:https://arxiv.org/abs/2511.16626
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author Grasdijk, Olivier
Kastelic, Jakob
Li, Jianhui
Timgren, Oskari
Wenz, Konrad
Yang, Yuanhang
Zhou, Perry
Kawall, David
Zelevinsky, Tanya
DeMille, David
author_facet Grasdijk, Olivier
Kastelic, Jakob
Li, Jianhui
Timgren, Oskari
Wenz, Konrad
Yang, Yuanhang
Zhou, Perry
Kawall, David
Zelevinsky, Tanya
DeMille, David
contents We present a hyperfine-resolved state preparation scheme for thallium fluoride (TlF) molecules based on microwave-driven adiabatic passage (AP) in a spatially varying electric field. This method enables efficient and robust population transfer between selected $\left|J,m_J=0\right\rangle$ hyperfine sublevels of the $X\,^1Σ^+_0$ ground state in a cryogenic molecular beam, a key requirement for the CeNTREX search for nuclear time-reversal symmetry violation. Two sequential stages of AP are implemented. The first transfers population from $J=0$ to $J=1$ at a local field of $173~\mathrm{V/cm}$, and the second transfers from $J=1$ to $J=2$ at $110~\mathrm{V/cm}$. Transfer efficiencies are quantified through laser-induced fluorescence, and accounting for residual population in excited rotational levels after a prior stage of rotational cooling. We achieve state transfer efficiencies of $0.92(6)$ and $1.05(5)$ for the first and second states of AP, respectively. This corresponds to a total efficiency of $0.97(8)$ for population transfer from $J=0$ to $J=2$. These results demonstrate robust and high-fidelity preparation of specific rotational/hyperfine states in TlF.
format Preprint
id arxiv_https___arxiv_org_abs_2511_16626
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Adiabatic passage of $^{205}$TlF with microwaves in a cryogenic beam
Grasdijk, Olivier
Kastelic, Jakob
Li, Jianhui
Timgren, Oskari
Wenz, Konrad
Yang, Yuanhang
Zhou, Perry
Kawall, David
Zelevinsky, Tanya
DeMille, David
Atomic Physics
We present a hyperfine-resolved state preparation scheme for thallium fluoride (TlF) molecules based on microwave-driven adiabatic passage (AP) in a spatially varying electric field. This method enables efficient and robust population transfer between selected $\left|J,m_J=0\right\rangle$ hyperfine sublevels of the $X\,^1Σ^+_0$ ground state in a cryogenic molecular beam, a key requirement for the CeNTREX search for nuclear time-reversal symmetry violation. Two sequential stages of AP are implemented. The first transfers population from $J=0$ to $J=1$ at a local field of $173~\mathrm{V/cm}$, and the second transfers from $J=1$ to $J=2$ at $110~\mathrm{V/cm}$. Transfer efficiencies are quantified through laser-induced fluorescence, and accounting for residual population in excited rotational levels after a prior stage of rotational cooling. We achieve state transfer efficiencies of $0.92(6)$ and $1.05(5)$ for the first and second states of AP, respectively. This corresponds to a total efficiency of $0.97(8)$ for population transfer from $J=0$ to $J=2$. These results demonstrate robust and high-fidelity preparation of specific rotational/hyperfine states in TlF.
title Adiabatic passage of $^{205}$TlF with microwaves in a cryogenic beam
topic Atomic Physics
url https://arxiv.org/abs/2511.16626