Accelerated Materials Discovery through Cost-Aware Bayesian Optimization of Real-World Indentation Workflows

Fuente: arXiv
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Main Authors: Chawla, Vivek, Puplampu, Stephen, Zhu, Haochen, Rack, Philip D., Penumadu, Dayakar, Kalinin, Sergei
Format: Preprint
Published: 2025
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author Chawla, Vivek
Puplampu, Stephen
Zhu, Haochen
Rack, Philip D.
Penumadu, Dayakar
Kalinin, Sergei
author_facet Chawla, Vivek
Puplampu, Stephen
Zhu, Haochen
Rack, Philip D.
Penumadu, Dayakar
Kalinin, Sergei
contents Accelerating the discovery of mechanical properties in combinatorial materials requires autonomous experimentation that accounts for both instrument behavior and experimental cost. Here, an automated nanoindentation (AE-NI) framework is developed and validated for adaptive mechanical mapping of combinatorial thin-film libraries. The method integrates heteroskedastic Gaussian-process modeling with cost-aware Bayesian optimization to dynamically select indentation locations and hold times, minimizing total testing time while preserving measurement accuracy. A detailed emulator and cost model capture the intrinsic penalties associated with lateral motion, drift stabilization, and reconfiguration-factors often neglected in conventional active-learning approaches. To prevent kernel-length-scale collapse caused by disparate time scales, a hierarchical meta-testing workflow combining local grid and global exploration is introduced. Implementation of the workflow is shown on a experimental Ta-Ti-Hf-Zr thin-film library. The proposed framework achieves nearly a thirty-fold improvement in property-mapping efficiency relative to grid-based indentation, demonstrating that incorporating cost and drift models into probabilistic planning substantially improves performance. This study establishes a generalizable strategy for optimizing experimental workflows in autonomous materials characterization and can be extended to other high-precision, drift-limited instruments.
format Preprint
id arxiv_https___arxiv_org_abs_2511_16930
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Accelerated Materials Discovery through Cost-Aware Bayesian Optimization of Real-World Indentation Workflows
Chawla, Vivek
Puplampu, Stephen
Zhu, Haochen
Rack, Philip D.
Penumadu, Dayakar
Kalinin, Sergei
Materials Science
Accelerating the discovery of mechanical properties in combinatorial materials requires autonomous experimentation that accounts for both instrument behavior and experimental cost. Here, an automated nanoindentation (AE-NI) framework is developed and validated for adaptive mechanical mapping of combinatorial thin-film libraries. The method integrates heteroskedastic Gaussian-process modeling with cost-aware Bayesian optimization to dynamically select indentation locations and hold times, minimizing total testing time while preserving measurement accuracy. A detailed emulator and cost model capture the intrinsic penalties associated with lateral motion, drift stabilization, and reconfiguration-factors often neglected in conventional active-learning approaches. To prevent kernel-length-scale collapse caused by disparate time scales, a hierarchical meta-testing workflow combining local grid and global exploration is introduced. Implementation of the workflow is shown on a experimental Ta-Ti-Hf-Zr thin-film library. The proposed framework achieves nearly a thirty-fold improvement in property-mapping efficiency relative to grid-based indentation, demonstrating that incorporating cost and drift models into probabilistic planning substantially improves performance. This study establishes a generalizable strategy for optimizing experimental workflows in autonomous materials characterization and can be extended to other high-precision, drift-limited instruments.
title Accelerated Materials Discovery through Cost-Aware Bayesian Optimization of Real-World Indentation Workflows
topic Materials Science
url https://arxiv.org/abs/2511.16930