Enhanced Efficiency of Intermediate-Band Semiconductor Solar Cells Embedded with Quantum Dot Superlattices

Fuente: arXiv
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Auteurs principaux: Petrosyan, Naira, Yeganyan, Lilit, Manaselyan, Aram, Mughnetsyan, Vram, Gudmundsson, Vidar, Kirakosyan, Albert
Format: Preprint
Publié: 2025
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author Petrosyan, Naira
Yeganyan, Lilit
Manaselyan, Aram
Mughnetsyan, Vram
Gudmundsson, Vidar
Kirakosyan, Albert
author_facet Petrosyan, Naira
Yeganyan, Lilit
Manaselyan, Aram
Mughnetsyan, Vram
Gudmundsson, Vidar
Kirakosyan, Albert
contents We present a multiscale approach for modeling an intermediate-band solar cell based on a GaAs-GaAlAs quantum dot superlattice of cubic symmetry. Our framework combines high-accuracy theoretical calculations of the superlattice band structure and miniband-related absorption coefficient with experimentally determined interband absorption data. The quantum-mechanically derived absorption spectrum is incorporated into a drift-diffusion transport model in COMSOL Multiphysics, where key processes, including thermal and radiative recombination, are taken into account. This integrated methodology enables realistic modeling of device performance. Our results identify an optimal superlattice constant of 14 nm, yielding a maximum solar cell efficiency of 13.3 percent. Further increase in the superlattice constant enhances the miniband-related absorption peak but reduces the generation rate in the n-type region, resulting in a net efficiency decrease. The proposed approach, integrating theoretical, experimental, and computational components, provides a reliable framework for assessing solar cells based on quantum dot superlattices.
format Preprint
id arxiv_https___arxiv_org_abs_2511_17151
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Enhanced Efficiency of Intermediate-Band Semiconductor Solar Cells Embedded with Quantum Dot Superlattices
Petrosyan, Naira
Yeganyan, Lilit
Manaselyan, Aram
Mughnetsyan, Vram
Gudmundsson, Vidar
Kirakosyan, Albert
Mesoscale and Nanoscale Physics
We present a multiscale approach for modeling an intermediate-band solar cell based on a GaAs-GaAlAs quantum dot superlattice of cubic symmetry. Our framework combines high-accuracy theoretical calculations of the superlattice band structure and miniband-related absorption coefficient with experimentally determined interband absorption data. The quantum-mechanically derived absorption spectrum is incorporated into a drift-diffusion transport model in COMSOL Multiphysics, where key processes, including thermal and radiative recombination, are taken into account. This integrated methodology enables realistic modeling of device performance. Our results identify an optimal superlattice constant of 14 nm, yielding a maximum solar cell efficiency of 13.3 percent. Further increase in the superlattice constant enhances the miniband-related absorption peak but reduces the generation rate in the n-type region, resulting in a net efficiency decrease. The proposed approach, integrating theoretical, experimental, and computational components, provides a reliable framework for assessing solar cells based on quantum dot superlattices.
title Enhanced Efficiency of Intermediate-Band Semiconductor Solar Cells Embedded with Quantum Dot Superlattices
topic Mesoscale and Nanoscale Physics
url https://arxiv.org/abs/2511.17151