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| Main Authors: | , , , , , , , , |
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| Format: | Preprint |
| Published: |
2025
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| Subjects: | |
| Online Access: | https://arxiv.org/abs/2511.20093 |
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| _version_ | 1866911441913643008 |
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| author | Valencia, Ana M. Kuechle, Theresa Tomoscheit, Maximiliam Finkelmeyer, Sarah Jasmin Utismenko, Olga Peneva, Kalina Presselt, Martin Soavi, Giancarlo Cocchi, Caterina |
| author_facet | Valencia, Ana M. Kuechle, Theresa Tomoscheit, Maximiliam Finkelmeyer, Sarah Jasmin Utismenko, Olga Peneva, Kalina Presselt, Martin Soavi, Giancarlo Cocchi, Caterina |
| contents | Hybrid heterostructures combining transition metal dichalcogenides (TMDs) with light-harvesting dyes are promising materials for next-generation optoelectronics. Yet, controlling and understanding interfacial charge transfer mechanisms in these complex systems remains a major challenge. Here, we investigate the microscopic origin of photoluminescence (PL) quenching in $\text{WSe}_2$ functionalized with a novel, strongly electron-deficient perylene monoimide dye, $\text{CN}_4\text{PMI}$. Experimentally, the hybridization induces a $\sim$97\% PL quenching in $\text{WSe}_2$, confirming substantial static charge transfer and increased $p$-doping from the dye. To isolate the dominant electronic mechanism, we investigate from first principles various interface morphologies, including differing molecular orientations and layer thicknesses. Our density-functional theory results confirm that $\text{CN}_4\text{PMI}$ acts as a strong electron acceptor, inducing $p$-doping and forming a type-II level alignment with all considered configurations, giving rise to a small or vanishing band gap. Based on these findings, we attribute the observed PL suppression in $\text{WSe}_2$ to these strong electronic interactions with the dye. Our study provides a clear and validated strategy for tailoring the electronic structure of TMDs through targeted, electron-deficient organic functionalization. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2511_20093 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | Photoluminescence Quenching in WSe$_2$ via p-Doping Induced by Functionalized Rylene Dyes Valencia, Ana M. Kuechle, Theresa Tomoscheit, Maximiliam Finkelmeyer, Sarah Jasmin Utismenko, Olga Peneva, Kalina Presselt, Martin Soavi, Giancarlo Cocchi, Caterina Materials Science Hybrid heterostructures combining transition metal dichalcogenides (TMDs) with light-harvesting dyes are promising materials for next-generation optoelectronics. Yet, controlling and understanding interfacial charge transfer mechanisms in these complex systems remains a major challenge. Here, we investigate the microscopic origin of photoluminescence (PL) quenching in $\text{WSe}_2$ functionalized with a novel, strongly electron-deficient perylene monoimide dye, $\text{CN}_4\text{PMI}$. Experimentally, the hybridization induces a $\sim$97\% PL quenching in $\text{WSe}_2$, confirming substantial static charge transfer and increased $p$-doping from the dye. To isolate the dominant electronic mechanism, we investigate from first principles various interface morphologies, including differing molecular orientations and layer thicknesses. Our density-functional theory results confirm that $\text{CN}_4\text{PMI}$ acts as a strong electron acceptor, inducing $p$-doping and forming a type-II level alignment with all considered configurations, giving rise to a small or vanishing band gap. Based on these findings, we attribute the observed PL suppression in $\text{WSe}_2$ to these strong electronic interactions with the dye. Our study provides a clear and validated strategy for tailoring the electronic structure of TMDs through targeted, electron-deficient organic functionalization. |
| title | Photoluminescence Quenching in WSe$_2$ via p-Doping Induced by Functionalized Rylene Dyes |
| topic | Materials Science |
| url | https://arxiv.org/abs/2511.20093 |