Stood-up drop to measure receding contact angles

Fuente: arXiv
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Main Authors: Díaz, Diego, Bhargava, Aman, Walz, Franziska, Sharifi, Azadeh, Sumally, Sajjad, Berger, Rüdiger, Kappl, Michael, Butt, Hans-Jürgen, Lohse, Detlef, Willers, Thomas, Sanjay, Vatsal, Vollmer, Doris
Format: Preprint
Published: 2025
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author Díaz, Diego
Bhargava, Aman
Walz, Franziska
Sharifi, Azadeh
Sumally, Sajjad
Berger, Rüdiger
Kappl, Michael
Butt, Hans-Jürgen
Lohse, Detlef
Willers, Thomas
Sanjay, Vatsal
Vollmer, Doris
author_facet Díaz, Diego
Bhargava, Aman
Walz, Franziska
Sharifi, Azadeh
Sumally, Sajjad
Berger, Rüdiger
Kappl, Michael
Butt, Hans-Jürgen
Lohse, Detlef
Willers, Thomas
Sanjay, Vatsal
Vollmer, Doris
contents The wetting behavior of drops on natural and industrial surfaces is determined by the advancing and receding contact angles. They are commonly measured by the sessile drop technique, also called goniometry, which doses liquid through a solid needle. Consequently, this method requires substantial drop volumes, long contact times, tends to be user-dependent, and is difficult to automate. Here, we propose the stood-up drop (SUD) technique as an alternative to measure receding contact angles. The method consists of depositing a liquid drop on a surface by a short liquid jet, at which it spreads radially forming a pancake-shaped film. Then the liquid retracts, forming a spherical cap drop shape (stood-up drop). At this quasi-equilibrium state, the contact angle ($θ_\text{SUD}$) closely resembles the receding contact angle measured by goniometry. Our method is suitable for a wide variety of surfaces from hydrophilic to hydrophobic, overcoming typical complications of goniometry such as needle-induced distortion of the drop shape, and it reduces user dependence. We delineate when the receding contact angle can be obtained by the stood-up method using Volume-of-Fluid (VoF) simulations that systematically vary viscosity, contact angle, and deposited drop volume. Finally, we provide simple scaling criteria to predict when the stood-up drop technique works.
format Preprint
id arxiv_https___arxiv_org_abs_2511_20259
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Stood-up drop to measure receding contact angles
Díaz, Diego
Bhargava, Aman
Walz, Franziska
Sharifi, Azadeh
Sumally, Sajjad
Berger, Rüdiger
Kappl, Michael
Butt, Hans-Jürgen
Lohse, Detlef
Willers, Thomas
Sanjay, Vatsal
Vollmer, Doris
Fluid Dynamics
The wetting behavior of drops on natural and industrial surfaces is determined by the advancing and receding contact angles. They are commonly measured by the sessile drop technique, also called goniometry, which doses liquid through a solid needle. Consequently, this method requires substantial drop volumes, long contact times, tends to be user-dependent, and is difficult to automate. Here, we propose the stood-up drop (SUD) technique as an alternative to measure receding contact angles. The method consists of depositing a liquid drop on a surface by a short liquid jet, at which it spreads radially forming a pancake-shaped film. Then the liquid retracts, forming a spherical cap drop shape (stood-up drop). At this quasi-equilibrium state, the contact angle ($θ_\text{SUD}$) closely resembles the receding contact angle measured by goniometry. Our method is suitable for a wide variety of surfaces from hydrophilic to hydrophobic, overcoming typical complications of goniometry such as needle-induced distortion of the drop shape, and it reduces user dependence. We delineate when the receding contact angle can be obtained by the stood-up method using Volume-of-Fluid (VoF) simulations that systematically vary viscosity, contact angle, and deposited drop volume. Finally, we provide simple scaling criteria to predict when the stood-up drop technique works.
title Stood-up drop to measure receding contact angles
topic Fluid Dynamics
url https://arxiv.org/abs/2511.20259