Antiferromagnetism and Kekulé valence bond order in the honeycomb optical Su-Schrieffer-Heeger-Hubbard model

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Hauptverfasser: Costa, Sohan Malkaruge, Cohen-Stead, Benjamin, Johnston, Steven
Format: Preprint
Veröffentlicht: 2025
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author Costa, Sohan Malkaruge
Cohen-Stead, Benjamin
Johnston, Steven
author_facet Costa, Sohan Malkaruge
Cohen-Stead, Benjamin
Johnston, Steven
contents The precise role of e-ph coupling in graphene and related materials on a honeycomb lattice is not yet fully understood, despite extensive research on these systems. Here, we perform sign-problem-free determinant quantum Monte Carlo (DQMC) simulations of the optical Su-Schrieffer-Heeger (oSSH)-Hubbard model on the honeycomb lattice, focusing on the parameters relevant to graphene. Performing finite-size scaling analyzes, we obtain the model's ground state phase diagram, which includes the semi-metal (SM), Kekulé Valence Bond Solid (KVBS), and anti-ferromagnetic (AFM) phases, as well as indications of a small KVBS/AFM coexistence region. We find that a weak to moderate Hubbard repulsion, tuned toward the SM-AFM critical value in the pure honeycomb Hubbard model, enhances KVBS correlations and can even stabilize the KVBS phase. Estimating the effective parameters for graphene places it in the SM region of the phase diagram, but near the SM-KVBS phase boundary. Notably, we predict that increasing either the on-site Hubbard repulsion or the e-ph coupling strength drives graphene toward the KVBS phase rather than the AFM phase, highlighting a synergistic effect that can be exploited to further control the remarkable properties of graphene and related materials.
format Preprint
id arxiv_https___arxiv_org_abs_2511_21440
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Antiferromagnetism and Kekulé valence bond order in the honeycomb optical Su-Schrieffer-Heeger-Hubbard model
Costa, Sohan Malkaruge
Cohen-Stead, Benjamin
Johnston, Steven
Strongly Correlated Electrons
The precise role of e-ph coupling in graphene and related materials on a honeycomb lattice is not yet fully understood, despite extensive research on these systems. Here, we perform sign-problem-free determinant quantum Monte Carlo (DQMC) simulations of the optical Su-Schrieffer-Heeger (oSSH)-Hubbard model on the honeycomb lattice, focusing on the parameters relevant to graphene. Performing finite-size scaling analyzes, we obtain the model's ground state phase diagram, which includes the semi-metal (SM), Kekulé Valence Bond Solid (KVBS), and anti-ferromagnetic (AFM) phases, as well as indications of a small KVBS/AFM coexistence region. We find that a weak to moderate Hubbard repulsion, tuned toward the SM-AFM critical value in the pure honeycomb Hubbard model, enhances KVBS correlations and can even stabilize the KVBS phase. Estimating the effective parameters for graphene places it in the SM region of the phase diagram, but near the SM-KVBS phase boundary. Notably, we predict that increasing either the on-site Hubbard repulsion or the e-ph coupling strength drives graphene toward the KVBS phase rather than the AFM phase, highlighting a synergistic effect that can be exploited to further control the remarkable properties of graphene and related materials.
title Antiferromagnetism and Kekulé valence bond order in the honeycomb optical Su-Schrieffer-Heeger-Hubbard model
topic Strongly Correlated Electrons
url https://arxiv.org/abs/2511.21440