The derivation of the Liouville equation from the Schrodinger equation and its implications

Fuente: arXiv
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Autor principal: Meilakhs, A. P.
Formato: Preprint
Publicado: 2025
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author Meilakhs, A. P.
author_facet Meilakhs, A. P.
contents We present a new way of deriving classical mechanics from quantum mechanics. A key feature of the method is its compatibility with the standard approach used to derive transition rates between quantum states due to interactions. We apply the developed method to derive the main formulas of physical kinetics. We observe that, through the Liouville equation, we can deduce the non-collision part of the Boltzmann equation, and that, through the matrix of transition rates, we can deduce the collision integral. As a final result of the manuscript, we derive the Boltzmann equation from the Schrödinger equation as a single piece of formal mathematical manipulation, without any non-rigorous plausible reasoning used to glue together its different parts.
format Preprint
id arxiv_https___arxiv_org_abs_2511_21601
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle The derivation of the Liouville equation from the Schrodinger equation and its implications
Meilakhs, A. P.
Quantum Physics
Other Condensed Matter
We present a new way of deriving classical mechanics from quantum mechanics. A key feature of the method is its compatibility with the standard approach used to derive transition rates between quantum states due to interactions. We apply the developed method to derive the main formulas of physical kinetics. We observe that, through the Liouville equation, we can deduce the non-collision part of the Boltzmann equation, and that, through the matrix of transition rates, we can deduce the collision integral. As a final result of the manuscript, we derive the Boltzmann equation from the Schrödinger equation as a single piece of formal mathematical manipulation, without any non-rigorous plausible reasoning used to glue together its different parts.
title The derivation of the Liouville equation from the Schrodinger equation and its implications
topic Quantum Physics
Other Condensed Matter
url https://arxiv.org/abs/2511.21601