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| Autori principali: | , , , , , , , , , , , , , |
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| Natura: | Preprint |
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2025
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| Accesso online: | https://arxiv.org/abs/2512.03785 |
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| _version_ | 1866915651553067008 |
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| author | Kiens, Ellen M. Gauquelin, Nicolas Annys, Arno van der Minne, Emma Bosch, Iris C. G. van den van Spronsen, Matthijs A. Zhang, Zezhong de Backer, Annick van Aert, Sandra Verbeeck, Jo Koster, Gertjan Mei, Bastian de Groot, Frank M. F. Baeumer, Christoph |
| author_facet | Kiens, Ellen M. Gauquelin, Nicolas Annys, Arno van der Minne, Emma Bosch, Iris C. G. van den van Spronsen, Matthijs A. Zhang, Zezhong de Backer, Annick van Aert, Sandra Verbeeck, Jo Koster, Gertjan Mei, Bastian de Groot, Frank M. F. Baeumer, Christoph |
| contents | Transition metal oxides exhibit a wide range of tunable electronic properties arising from the complex interplay of charge, spin, and lattice degrees of freedom, governed by their $d$ orbital configurations, making them particularly interesting for oxide electronics and (electro)catalysis. Perovskite oxide heterointerfaces offer a promising route to engineer these orbital states. In this work, we tune the Co $3d$ orbital occupancy in LaCoO$_3$ from a partial $d^7$ to a partial $d^5$ state through interfacial engineering with LaTiO$_3$, LaMnO$_3$, LaAlO$_3$ and LaNiO$_3$. Using X-ray absorption spectroscopy combined with charge transfer multiplet calculations, we identify differences in the Co valence and spin state for the series of oxide heterostructures. LaTiO$_3$ and LaMnO$_3$ interfaces result in interfacial charge transfer towards LaCoO$_3$, resulting in a partial $d^7$ orbital occupancy, while a LaNiO$_3$ interface results in a partial Co $d^5$ occupancy. Strikingly, a LaAlO$_3$ spacer layer between LaNiO$_3$ and LaCoO$_3$ results in a Co $d^6$ low spin state. These results indicate that the Co spin state, like the valence state, is governed by the interfacial environment. High-resolution scanning transmission electron microscopy imaging reveals a clear connection between strain and spin configuration, emphasizing the importance of structural control at oxide interfaces. Overall, this work demonstrates that interfacial engineering simultaneously governs orbital occupancy and spin state in correlated oxides, advancing spin-engineering strategies in correlated oxides and offering new insights for the rational design of functional oxide heterostructures. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2512_03785 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | Interfacial Control of Orbital Occupancy and Spin State in LaCoO$_3$ Kiens, Ellen M. Gauquelin, Nicolas Annys, Arno van der Minne, Emma Bosch, Iris C. G. van den van Spronsen, Matthijs A. Zhang, Zezhong de Backer, Annick van Aert, Sandra Verbeeck, Jo Koster, Gertjan Mei, Bastian de Groot, Frank M. F. Baeumer, Christoph Materials Science Transition metal oxides exhibit a wide range of tunable electronic properties arising from the complex interplay of charge, spin, and lattice degrees of freedom, governed by their $d$ orbital configurations, making them particularly interesting for oxide electronics and (electro)catalysis. Perovskite oxide heterointerfaces offer a promising route to engineer these orbital states. In this work, we tune the Co $3d$ orbital occupancy in LaCoO$_3$ from a partial $d^7$ to a partial $d^5$ state through interfacial engineering with LaTiO$_3$, LaMnO$_3$, LaAlO$_3$ and LaNiO$_3$. Using X-ray absorption spectroscopy combined with charge transfer multiplet calculations, we identify differences in the Co valence and spin state for the series of oxide heterostructures. LaTiO$_3$ and LaMnO$_3$ interfaces result in interfacial charge transfer towards LaCoO$_3$, resulting in a partial $d^7$ orbital occupancy, while a LaNiO$_3$ interface results in a partial Co $d^5$ occupancy. Strikingly, a LaAlO$_3$ spacer layer between LaNiO$_3$ and LaCoO$_3$ results in a Co $d^6$ low spin state. These results indicate that the Co spin state, like the valence state, is governed by the interfacial environment. High-resolution scanning transmission electron microscopy imaging reveals a clear connection between strain and spin configuration, emphasizing the importance of structural control at oxide interfaces. Overall, this work demonstrates that interfacial engineering simultaneously governs orbital occupancy and spin state in correlated oxides, advancing spin-engineering strategies in correlated oxides and offering new insights for the rational design of functional oxide heterostructures. |
| title | Interfacial Control of Orbital Occupancy and Spin State in LaCoO$_3$ |
| topic | Materials Science |
| url | https://arxiv.org/abs/2512.03785 |