Non-radiative energy transfer between boron vacancies in hexagonal boron nitride and other 2D materials

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Main Authors: Jules, Fraunié, Glazov, Mikhail M., Roux, Sébastien, Torres-Dias, Abraao Cefas, Crunteanu-Stanescu, Cora, Fournier, Tom, Dehaghani, Maryam S., Clua-Provost, Tristan, Lagarde, Delphine, Lombez, Laurent, Marie, Xavier, Lassagne, Benjamin, Poirier, Thomas, Edgar, James H., Jacques, Vincent, Robert, Cedric
Format: Preprint
Published: 2025
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author Jules, Fraunié
Glazov, Mikhail M.
Roux, Sébastien
Torres-Dias, Abraao Cefas
Crunteanu-Stanescu, Cora
Fournier, Tom
Dehaghani, Maryam S.
Clua-Provost, Tristan
Lagarde, Delphine
Lombez, Laurent
Marie, Xavier
Lassagne, Benjamin
Poirier, Thomas
Edgar, James H.
Jacques, Vincent
Robert, Cedric
author_facet Jules, Fraunié
Glazov, Mikhail M.
Roux, Sébastien
Torres-Dias, Abraao Cefas
Crunteanu-Stanescu, Cora
Fournier, Tom
Dehaghani, Maryam S.
Clua-Provost, Tristan
Lagarde, Delphine
Lombez, Laurent
Marie, Xavier
Lassagne, Benjamin
Poirier, Thomas
Edgar, James H.
Jacques, Vincent
Robert, Cedric
contents Boron vacancies ($V_B^-$) in hexagonal boron nitride (hBN) have emerged as a promising platform for two-dimensional quantum sensors capable of operating at atomic-scale proximity. However, the mechanisms responsible for photoluminescence quenching in thin hBN sensing layers when placed in contact with absorptive materials remain largely unexplored. In this Letter, we investigate non-radiative Förster resonance energy transfer (FRET) between $V_B^-$ centers and either monolayer graphene or 2D semiconductors. Strikingly, we find that the FRET rate is negligible for hBN sensing layers thicker than 3 nm, highlighting the potential of $V_B^-$ centers for integration into ultra-thin quantum sensors within van der Waals heterostructures. Furthermore, we experimentally extract the intrinsic radiative decay rate of $V_B^-$ defects.
format Preprint
id arxiv_https___arxiv_org_abs_2512_03970
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Non-radiative energy transfer between boron vacancies in hexagonal boron nitride and other 2D materials
Jules, Fraunié
Glazov, Mikhail M.
Roux, Sébastien
Torres-Dias, Abraao Cefas
Crunteanu-Stanescu, Cora
Fournier, Tom
Dehaghani, Maryam S.
Clua-Provost, Tristan
Lagarde, Delphine
Lombez, Laurent
Marie, Xavier
Lassagne, Benjamin
Poirier, Thomas
Edgar, James H.
Jacques, Vincent
Robert, Cedric
Materials Science
Mesoscale and Nanoscale Physics
Quantum Physics
Boron vacancies ($V_B^-$) in hexagonal boron nitride (hBN) have emerged as a promising platform for two-dimensional quantum sensors capable of operating at atomic-scale proximity. However, the mechanisms responsible for photoluminescence quenching in thin hBN sensing layers when placed in contact with absorptive materials remain largely unexplored. In this Letter, we investigate non-radiative Förster resonance energy transfer (FRET) between $V_B^-$ centers and either monolayer graphene or 2D semiconductors. Strikingly, we find that the FRET rate is negligible for hBN sensing layers thicker than 3 nm, highlighting the potential of $V_B^-$ centers for integration into ultra-thin quantum sensors within van der Waals heterostructures. Furthermore, we experimentally extract the intrinsic radiative decay rate of $V_B^-$ defects.
title Non-radiative energy transfer between boron vacancies in hexagonal boron nitride and other 2D materials
topic Materials Science
Mesoscale and Nanoscale Physics
Quantum Physics
url https://arxiv.org/abs/2512.03970