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Main Authors: Bulanadi, Ralph, Checa, Marti, Wang, Michelle, Rothen, Franck, Lasseter, John, Harris, Sumner B., Sando, Daniel, Nagarajan, Valanoor, Collins, Liam, Jesse, Stephen, Vasudevan, Rama, Liu, Yongtao
Format: Preprint
Published: 2025
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Online Access:https://arxiv.org/abs/2512.09249
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author Bulanadi, Ralph
Checa, Marti
Wang, Michelle
Rothen, Franck
Lasseter, John
Harris, Sumner B.
Sando, Daniel
Nagarajan, Valanoor
Collins, Liam
Jesse, Stephen
Vasudevan, Rama
Liu, Yongtao
author_facet Bulanadi, Ralph
Checa, Marti
Wang, Michelle
Rothen, Franck
Lasseter, John
Harris, Sumner B.
Sando, Daniel
Nagarajan, Valanoor
Collins, Liam
Jesse, Stephen
Vasudevan, Rama
Liu, Yongtao
contents The functional properties of ferroelectric materials are strongly influenced by ferroelectric polarization orientation; as such, access to consistent and precise characterization of polarization vectors is of substantial importance to ferroelectrics research. Here, we develop a fully automated three-dimensional piezoresponse force microscopy (Auto-3DPFM) technique automating all essential steps in interferometric PFM for 3D polarization vector characterization, including laser alignment, tip calibration and approach, image acquisition, polarization vector reconstruction, and visualization. The automation reduces the experimental burden of ferroelectric polarization vector characterization, while the back-and-forth calibration ensures consistency and reproducibility of 3D polarization reconstruction. An algorithmic workflow is also developed to identify domain walls and calculate their characteristic angles via a spatial vector-angle-difference method, presenting one unique capability enabled by Auto-3DPFM that is not accessible with traditional PFM techniques. Beyond representing a significant step forward in 3D polarization mapping, Auto-3DPFM promises to accelerate discovery via high-throughput and autonomous characterization in ferroelectric materials research. When integrated with machine learning and adaptive sampling strategies in self-driving labs, Auto-3DPFM will serve as a valuable tool for advancing ferroelectric physics and microelectronics development.
format Preprint
id arxiv_https___arxiv_org_abs_2512_09249
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Auto-3DPFM: Automating Polarization-Vector Mapping at the Nanoscale
Bulanadi, Ralph
Checa, Marti
Wang, Michelle
Rothen, Franck
Lasseter, John
Harris, Sumner B.
Sando, Daniel
Nagarajan, Valanoor
Collins, Liam
Jesse, Stephen
Vasudevan, Rama
Liu, Yongtao
Materials Science
The functional properties of ferroelectric materials are strongly influenced by ferroelectric polarization orientation; as such, access to consistent and precise characterization of polarization vectors is of substantial importance to ferroelectrics research. Here, we develop a fully automated three-dimensional piezoresponse force microscopy (Auto-3DPFM) technique automating all essential steps in interferometric PFM for 3D polarization vector characterization, including laser alignment, tip calibration and approach, image acquisition, polarization vector reconstruction, and visualization. The automation reduces the experimental burden of ferroelectric polarization vector characterization, while the back-and-forth calibration ensures consistency and reproducibility of 3D polarization reconstruction. An algorithmic workflow is also developed to identify domain walls and calculate their characteristic angles via a spatial vector-angle-difference method, presenting one unique capability enabled by Auto-3DPFM that is not accessible with traditional PFM techniques. Beyond representing a significant step forward in 3D polarization mapping, Auto-3DPFM promises to accelerate discovery via high-throughput and autonomous characterization in ferroelectric materials research. When integrated with machine learning and adaptive sampling strategies in self-driving labs, Auto-3DPFM will serve as a valuable tool for advancing ferroelectric physics and microelectronics development.
title Auto-3DPFM: Automating Polarization-Vector Mapping at the Nanoscale
topic Materials Science
url https://arxiv.org/abs/2512.09249