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| Format: | Preprint |
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2025
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| Online Access: | https://arxiv.org/abs/2512.09426 |
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| _version_ | 1866911311198158848 |
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| author | Bazhlekov, Ivan Bazhlekova, Emilia |
| author_facet | Bazhlekov, Ivan Bazhlekova, Emilia |
| contents | The mathematical model of surfactant adsorption under mixed barrier-diffusion control is analyzed using techniques from fractional calculus. The kinetic models of Henry, Langmuir, Frumkin, Volmer and van der Waals are considered. First, treating the Ward-Tordai integral equation as a fractional order one, the partial differential model is transformed into a single fractional ordinary differential equation for the adsorption. A transformation of the obtained equation is proposed that reduces the number of parameters to two dimensionless groups (at Frumkin and van der Waals models a third parameter appears). In the simplest case of Henry adsorption isotherm the fractional differential model depends on a single dimensionless group and an exact solution exists, represented in terms of Mittag-Leffler functions. Based on this solution, second order asymptotes (at small values of the adsorption) are derived for the other models. The asymptotes of the adsorption result in a higher order asymptotes for the surface pressure (surface tension). For small surface coverage, all considered models converge to the Henry model's predictions, making it a universal first-order approximation for the surface tension. Next, the fractional differential model is written as an integral equation %of fractional order that can be considered as a generalization of the well-known Ward-Tordai equation to the case of barrier-diffusion control. For computer simulation of the obtained integral equation a predictor-corrector numerical method is developed and numerical results are presented and discussed. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2512_09426 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | Fractional calculus approach to models of adsorption: Barrier-diffusion control Bazhlekov, Ivan Bazhlekova, Emilia Analysis of PDEs Mathematical Physics The mathematical model of surfactant adsorption under mixed barrier-diffusion control is analyzed using techniques from fractional calculus. The kinetic models of Henry, Langmuir, Frumkin, Volmer and van der Waals are considered. First, treating the Ward-Tordai integral equation as a fractional order one, the partial differential model is transformed into a single fractional ordinary differential equation for the adsorption. A transformation of the obtained equation is proposed that reduces the number of parameters to two dimensionless groups (at Frumkin and van der Waals models a third parameter appears). In the simplest case of Henry adsorption isotherm the fractional differential model depends on a single dimensionless group and an exact solution exists, represented in terms of Mittag-Leffler functions. Based on this solution, second order asymptotes (at small values of the adsorption) are derived for the other models. The asymptotes of the adsorption result in a higher order asymptotes for the surface pressure (surface tension). For small surface coverage, all considered models converge to the Henry model's predictions, making it a universal first-order approximation for the surface tension. Next, the fractional differential model is written as an integral equation %of fractional order that can be considered as a generalization of the well-known Ward-Tordai equation to the case of barrier-diffusion control. For computer simulation of the obtained integral equation a predictor-corrector numerical method is developed and numerical results are presented and discussed. |
| title | Fractional calculus approach to models of adsorption: Barrier-diffusion control |
| topic | Analysis of PDEs Mathematical Physics |
| url | https://arxiv.org/abs/2512.09426 |