Diversity in the haziness and chemistry of temperate sub-Neptunes

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Main Authors: Roy, Pierre-Alexis, Benneke, Björn, Fournier-Tondreau, Marylou, Coulombe, Louis-Philippe, Piaulet-Ghorayeb, Caroline, Lafrenière, David, Allart, Romain, Cowan, Nicolas B., Dang, Lisa, Johnstone, Doug, Langeveld, Adam B., Pelletier, Stefan, Radica, Michael, Taylor, Jake, Albert, Loïc, Doyon, René, Flagg, Laura, Jayawardhana, Ray, MacDonald, Ryan J., Turner, Jake D.
Format: Preprint
Published: 2025
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author Roy, Pierre-Alexis
Benneke, Björn
Fournier-Tondreau, Marylou
Coulombe, Louis-Philippe
Piaulet-Ghorayeb, Caroline
Lafrenière, David
Allart, Romain
Cowan, Nicolas B.
Dang, Lisa
Johnstone, Doug
Langeveld, Adam B.
Pelletier, Stefan
Radica, Michael
Taylor, Jake
Albert, Loïc
Doyon, René
Flagg, Laura
Jayawardhana, Ray
MacDonald, Ryan J.
Turner, Jake D.
author_facet Roy, Pierre-Alexis
Benneke, Björn
Fournier-Tondreau, Marylou
Coulombe, Louis-Philippe
Piaulet-Ghorayeb, Caroline
Lafrenière, David
Allart, Romain
Cowan, Nicolas B.
Dang, Lisa
Johnstone, Doug
Langeveld, Adam B.
Pelletier, Stefan
Radica, Michael
Taylor, Jake
Albert, Loïc
Doyon, René
Flagg, Laura
Jayawardhana, Ray
MacDonald, Ryan J.
Turner, Jake D.
contents Recent transit observations of K2-18b and TOI-270d revealed strong molecular absorption signatures, lending credence to the idea that temperate sub-Neptunes (T$_\mathrm{eq}$=250-400K) have upper atmospheres mostly free of aerosols. These observations also indicated higher-than-expected CO$_2$ abundances on both planets, implying bulk compositions with high water mass fractions. However, it remains unclear whether these findings hold true for all temperate sub-Neptunes. Here, we present the JWST NIRSpec/PRISM 0.7-5.4$\mathbfμ$m transmission spectrum of a third temperate sub-Neptune, the 2.4R$_\oplus$ planet LP 791-18c (T$_\mathrm{eq}$=355K), which is even more favorable for atmospheric characterization thanks to its small M6 host star. Intriguingly, despite LP 791-18c's radius, mass, and equilibrium temperature being in between those of K2-18b and TOI-270d, we find a drastically different transmission spectrum. While we also detect methane on LP 791-18c, its transit spectrum is dominated by strong haze scattering and there is no discernible CO$_2$ absorption. Overall, we infer a deep metal-enriched atmosphere (246-415$\times$solar) for LP 791-18c, with a CO$_2$-to-CH$_4$ ratio smaller than 0.07 (at 2$σ$), indicating less H$_2$O in the deep envelope of LP 791-18c and implying a relatively dry formation inside the water ice-line. These results show that sub-Neptunes that are near-analogues in density and temperature can show drastically different aerosols and envelope chemistry, and are intrinsically diverse beyond a simple temperature dependence.
format Preprint
id arxiv_https___arxiv_org_abs_2512_10876
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Diversity in the haziness and chemistry of temperate sub-Neptunes
Roy, Pierre-Alexis
Benneke, Björn
Fournier-Tondreau, Marylou
Coulombe, Louis-Philippe
Piaulet-Ghorayeb, Caroline
Lafrenière, David
Allart, Romain
Cowan, Nicolas B.
Dang, Lisa
Johnstone, Doug
Langeveld, Adam B.
Pelletier, Stefan
Radica, Michael
Taylor, Jake
Albert, Loïc
Doyon, René
Flagg, Laura
Jayawardhana, Ray
MacDonald, Ryan J.
Turner, Jake D.
Earth and Planetary Astrophysics
Recent transit observations of K2-18b and TOI-270d revealed strong molecular absorption signatures, lending credence to the idea that temperate sub-Neptunes (T$_\mathrm{eq}$=250-400K) have upper atmospheres mostly free of aerosols. These observations also indicated higher-than-expected CO$_2$ abundances on both planets, implying bulk compositions with high water mass fractions. However, it remains unclear whether these findings hold true for all temperate sub-Neptunes. Here, we present the JWST NIRSpec/PRISM 0.7-5.4$\mathbfμ$m transmission spectrum of a third temperate sub-Neptune, the 2.4R$_\oplus$ planet LP 791-18c (T$_\mathrm{eq}$=355K), which is even more favorable for atmospheric characterization thanks to its small M6 host star. Intriguingly, despite LP 791-18c's radius, mass, and equilibrium temperature being in between those of K2-18b and TOI-270d, we find a drastically different transmission spectrum. While we also detect methane on LP 791-18c, its transit spectrum is dominated by strong haze scattering and there is no discernible CO$_2$ absorption. Overall, we infer a deep metal-enriched atmosphere (246-415$\times$solar) for LP 791-18c, with a CO$_2$-to-CH$_4$ ratio smaller than 0.07 (at 2$σ$), indicating less H$_2$O in the deep envelope of LP 791-18c and implying a relatively dry formation inside the water ice-line. These results show that sub-Neptunes that are near-analogues in density and temperature can show drastically different aerosols and envelope chemistry, and are intrinsically diverse beyond a simple temperature dependence.
title Diversity in the haziness and chemistry of temperate sub-Neptunes
topic Earth and Planetary Astrophysics
url https://arxiv.org/abs/2512.10876