First mapping of prebiotic molecule CH2NH in a pre-stellar core

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Main Authors: Lin, Yuxin, Spezzano, Silvia, Sipilä, Olli, Pineda, Jaime E., Caselli, Paola
Format: Preprint
Published: 2025
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author Lin, Yuxin
Spezzano, Silvia
Sipilä, Olli
Pineda, Jaime E.
Caselli, Paola
author_facet Lin, Yuxin
Spezzano, Silvia
Sipilä, Olli
Pineda, Jaime E.
Caselli, Paola
contents We present the first spatially resolved map of methanimine CH2NH in the prestellar core L1544 using the IRAM 30m telescope. The 2$_{0,2}$-1$_{0,1}$ line at 127 GHz was mapped with 20" resolution ($\sim$2800 au), revealing extended CH2NH emission across the core. The peak line intensity coincides with the well-known c-C3H2 peak, while the integrated intensity peaks between the HNCO and dust continuum peaks due to broader linewidths in the latter region. Column densities of CH2NH are $\sim$(0.5-1.4$\times$)10$^{12}$ cm$^{-2}$, corresponding to fractional abundances of $5\times10^{-11}$-$1\times10^{-10}$, with a trend decreasing from the southern, carbon-chain rich region to the dust and HNCO peak in the north. Comparison with complementary molecular maps and the gas-grain chemical model of Sipilä et al. suggests that neutral-neutral gas-phase reactions and dissociative recombination dominate in the outer carbon-chain shell. This study demonstrates that CH2NH, a simple nitrogen- and carbon-bearing molecule previously detected with pointed observations in other cold cores, is present and spatially extended in the evolved pre-stellar core L1544. This indicates that prebiotic nitrogen-carbon chemistry continues efficiently up to the onset of gravitational collapse, providing key constraints for astrochemical models and the early stages of chemical complexity leading to amino acids.
format Preprint
id arxiv_https___arxiv_org_abs_2512_12396
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle First mapping of prebiotic molecule CH2NH in a pre-stellar core
Lin, Yuxin
Spezzano, Silvia
Sipilä, Olli
Pineda, Jaime E.
Caselli, Paola
Astrophysics of Galaxies
Solar and Stellar Astrophysics
We present the first spatially resolved map of methanimine CH2NH in the prestellar core L1544 using the IRAM 30m telescope. The 2$_{0,2}$-1$_{0,1}$ line at 127 GHz was mapped with 20" resolution ($\sim$2800 au), revealing extended CH2NH emission across the core. The peak line intensity coincides with the well-known c-C3H2 peak, while the integrated intensity peaks between the HNCO and dust continuum peaks due to broader linewidths in the latter region. Column densities of CH2NH are $\sim$(0.5-1.4$\times$)10$^{12}$ cm$^{-2}$, corresponding to fractional abundances of $5\times10^{-11}$-$1\times10^{-10}$, with a trend decreasing from the southern, carbon-chain rich region to the dust and HNCO peak in the north. Comparison with complementary molecular maps and the gas-grain chemical model of Sipilä et al. suggests that neutral-neutral gas-phase reactions and dissociative recombination dominate in the outer carbon-chain shell. This study demonstrates that CH2NH, a simple nitrogen- and carbon-bearing molecule previously detected with pointed observations in other cold cores, is present and spatially extended in the evolved pre-stellar core L1544. This indicates that prebiotic nitrogen-carbon chemistry continues efficiently up to the onset of gravitational collapse, providing key constraints for astrochemical models and the early stages of chemical complexity leading to amino acids.
title First mapping of prebiotic molecule CH2NH in a pre-stellar core
topic Astrophysics of Galaxies
Solar and Stellar Astrophysics
url https://arxiv.org/abs/2512.12396