Extended dissipaton theory for higher-order bath couplings and application to non-Condon spectroscopy with anharmonicity
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arXiv
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| Autori principali: | , , , , |
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| Natura: | Preprint |
| Pubblicazione: |
2025
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| _version_ | 1866917145227558912 |
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| author | Zhu, Zi-Fan Su, Yu Wang, Yao Xu, Rui-Xue Yan, YiJing |
| author_facet | Zhu, Zi-Fan Su, Yu Wang, Yao Xu, Rui-Xue Yan, YiJing |
| contents | In this work, we develop an extended dissipaton theory that generalizes the environmental couplings beyond the conventional linear and quadratic forms, enabling the treatment of arbitrary order of bath couplings. Applying this theoretical framework to the condensed-phase non-Condon spectroscopy, we demonstrate the interplay of anharmonicity, non-Condon and solvent effects on optical spectra. Precise simulations are carried out with high efficiency on linear absorption spectra involving the above mentioned correlated effects. We exhibit how an anharmonic potential modulates the vibronic feature, offering insights into the role of nonlinear environmental couplings in spectroscopic signatures and exemplifying the success of the extended dissipaton formalism as an exact and efficient method for higher-order bath couplings. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2512_12584 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | Extended dissipaton theory for higher-order bath couplings and application to non-Condon spectroscopy with anharmonicity Zhu, Zi-Fan Su, Yu Wang, Yao Xu, Rui-Xue Yan, YiJing Chemical Physics Quantum Physics In this work, we develop an extended dissipaton theory that generalizes the environmental couplings beyond the conventional linear and quadratic forms, enabling the treatment of arbitrary order of bath couplings. Applying this theoretical framework to the condensed-phase non-Condon spectroscopy, we demonstrate the interplay of anharmonicity, non-Condon and solvent effects on optical spectra. Precise simulations are carried out with high efficiency on linear absorption spectra involving the above mentioned correlated effects. We exhibit how an anharmonic potential modulates the vibronic feature, offering insights into the role of nonlinear environmental couplings in spectroscopic signatures and exemplifying the success of the extended dissipaton formalism as an exact and efficient method for higher-order bath couplings. |
| title | Extended dissipaton theory for higher-order bath couplings and application to non-Condon spectroscopy with anharmonicity |
| topic | Chemical Physics Quantum Physics |
| url | https://arxiv.org/abs/2512.12584 |