Hund's coupling driven nature of magnetism in negative charge transfer material, $\mathrm{SrCoO_3}$
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| Format: | Preprint |
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2025
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| author | Sharma, Jyotsana Bhardwaj, Shivani Pandey, Sudhir K |
| author_facet | Sharma, Jyotsana Bhardwaj, Shivani Pandey, Sudhir K |
| contents | In this work, we investigate the microscopic origin of magnetism in $\mathrm{SrCoO_3}$ by incorporating electronic correlations within the dynamical mean-field theory (DMFT) framework. We note a remarkable agreement of the calculated magnetic observables ( saturation magnetization $\sim$2.4 $μ_B$; magnetic transition temperature, $T_c$$\sim$350 K) with the experimental results. The system exhibits Hund's coupling-induced strong quasiparticle mass enhancements of upto $m^*/m$ $\sim$7 for Co 3$d$ states, with the largest renormalization occurring in the majority spin $t_{2g}$ orbitals, marking the onset of orbital-selectivity. Our results reveal a Stoner-$like$ collapse of exchange splitting that drives the loss of long-range ferromagnetic order at $T_c$. The breakdown of Fermi-liquid behavior down to $T$$\sim$100 K suggests a suppressed coherence scale. Local magnetic moment originates from a mixed-spin configuration formed through dynamical fluctuation between intermediate-spin and high-spin states. Large charge fluctuations ($\langle$$Δ$N$^2$$\rangle$$\sim$0.6) together with heavy quasiparticles establish the correlation effects regime, governed predominantly by Hund's physics in $\mathrm{SrCoO_3}$. |
| format | Preprint |
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arxiv_https___arxiv_org_abs_2512_12808 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | Hund's coupling driven nature of magnetism in negative charge transfer material, $\mathrm{SrCoO_3}$ Sharma, Jyotsana Bhardwaj, Shivani Pandey, Sudhir K Strongly Correlated Electrons In this work, we investigate the microscopic origin of magnetism in $\mathrm{SrCoO_3}$ by incorporating electronic correlations within the dynamical mean-field theory (DMFT) framework. We note a remarkable agreement of the calculated magnetic observables ( saturation magnetization $\sim$2.4 $μ_B$; magnetic transition temperature, $T_c$$\sim$350 K) with the experimental results. The system exhibits Hund's coupling-induced strong quasiparticle mass enhancements of upto $m^*/m$ $\sim$7 for Co 3$d$ states, with the largest renormalization occurring in the majority spin $t_{2g}$ orbitals, marking the onset of orbital-selectivity. Our results reveal a Stoner-$like$ collapse of exchange splitting that drives the loss of long-range ferromagnetic order at $T_c$. The breakdown of Fermi-liquid behavior down to $T$$\sim$100 K suggests a suppressed coherence scale. Local magnetic moment originates from a mixed-spin configuration formed through dynamical fluctuation between intermediate-spin and high-spin states. Large charge fluctuations ($\langle$$Δ$N$^2$$\rangle$$\sim$0.6) together with heavy quasiparticles establish the correlation effects regime, governed predominantly by Hund's physics in $\mathrm{SrCoO_3}$. |
| title | Hund's coupling driven nature of magnetism in negative charge transfer material, $\mathrm{SrCoO_3}$ |
| topic | Strongly Correlated Electrons |
| url | https://arxiv.org/abs/2512.12808 |