Nucleation suppression by charge screening on grain boundaries: a kinetic model for bulk imprint in polycrystalline ferroelectric thin films

Fuente: arXiv
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Autori principali: Tian, Huanhuan, Yang, Jianguo, Liu, Ming
Natura: Preprint
Pubblicazione: 2025
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author Tian, Huanhuan
Yang, Jianguo
Liu, Ming
author_facet Tian, Huanhuan
Yang, Jianguo
Liu, Ming
contents The imprint effect, a significant reliability challenge in ferroelectric memories, manifests as a shift in the coercive field during retention and endurance tests, ultimately degrading the usable memory window. \rv{While traditional models attribute imprint primarily to charge screening at the interface between the dead layer and the ferroelectric film, the contribution from grain boundaries has been largely overlooked. This work advances a bulk imprint mechanism by establishing a phase-field model, which demonstrates that the tuning of domain nuclei near grain boundaries via charge screening consistently explains the imprint process and aligns with key experimental trends.} These findings provide novel insights into the imprint process and advance the understanding of reliability issues in ferroelectric memory devices.
format Preprint
id arxiv_https___arxiv_org_abs_2512_13748
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Nucleation suppression by charge screening on grain boundaries: a kinetic model for bulk imprint in polycrystalline ferroelectric thin films
Tian, Huanhuan
Yang, Jianguo
Liu, Ming
Materials Science
The imprint effect, a significant reliability challenge in ferroelectric memories, manifests as a shift in the coercive field during retention and endurance tests, ultimately degrading the usable memory window. \rv{While traditional models attribute imprint primarily to charge screening at the interface between the dead layer and the ferroelectric film, the contribution from grain boundaries has been largely overlooked. This work advances a bulk imprint mechanism by establishing a phase-field model, which demonstrates that the tuning of domain nuclei near grain boundaries via charge screening consistently explains the imprint process and aligns with key experimental trends.} These findings provide novel insights into the imprint process and advance the understanding of reliability issues in ferroelectric memory devices.
title Nucleation suppression by charge screening on grain boundaries: a kinetic model for bulk imprint in polycrystalline ferroelectric thin films
topic Materials Science
url https://arxiv.org/abs/2512.13748