ExoMol line lists -- LXIII: ExoMol line lists for 12 isotopologues of CO$_2$
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| Main Authors: | , , , , , , , , , , , |
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| Format: | Preprint |
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2025
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| _version_ | 1866918282667229184 |
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| author | Yurchenko, Sergei N. Barnfield, Marco G. Bowesman, Charles A. Brady, Ryan P. Guest, Elizabeth R. Kefala, Kyriaki Ni, Qing-He Perri, Armando N. Smola, Oleksiy A. Solokov, Andrei Tao, Chenyi Tennyson, Jonathan |
| author_facet | Yurchenko, Sergei N. Barnfield, Marco G. Bowesman, Charles A. Brady, Ryan P. Guest, Elizabeth R. Kefala, Kyriaki Ni, Qing-He Perri, Armando N. Smola, Oleksiy A. Solokov, Andrei Tao, Chenyi Tennyson, Jonathan |
| contents | Extensive rovibrational line lists are constructed for 12 isotopologues of carbon dioxide: $^{12}$C$^{16}$O$_2$, $^{13}$C$^{16}$O$_2$, $^{12}$C$^{17}$O$_2$, $^{13}$C$^{17}$O$_2$, $^{12}$C$^{18}$O$_2$, $^{13}$C$^{18}$O$_2$, $^{16}$O$^{12}$C$^{17}$O, $^{16}$O$^{12}$C$^{18}$O, $^{16}$O$^{13}$C$^{17}$O, $^{16}$O$^{13}$C$^{18}$O, $^{17}$O$^{12}$C$^{18}$O, and $^{17}$O$^{13}$C$^{18}$O. The variational program TROVE was employed together with an exact kinetic energy operator, accurate empirical potential energy surface (Ames-2) and the ab initio dipole moment surface Ames-2021-40K. Empirical energy levels from the most recent MARVEL analyses, as well as from the HITRAN and CDSD databases, are used to replace calculated values where available. The line lists are further supplemented by assigning AFGL quantum numbers using machine-learning based estimators. The resulting data were employed to generate opacities with four radiative transfer codes, TauREx, ARCiS, NEMESIS, and petitRADTRANS, both for individual isotopologues and for CO$_2$ at terrestrial isotopic natural abundance. All line lists and associated data are available at www.exomol.com. |
| format | Preprint |
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arxiv_https___arxiv_org_abs_2512_13889 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | ExoMol line lists -- LXIII: ExoMol line lists for 12 isotopologues of CO$_2$ Yurchenko, Sergei N. Barnfield, Marco G. Bowesman, Charles A. Brady, Ryan P. Guest, Elizabeth R. Kefala, Kyriaki Ni, Qing-He Perri, Armando N. Smola, Oleksiy A. Solokov, Andrei Tao, Chenyi Tennyson, Jonathan Earth and Planetary Astrophysics Astrophysics of Galaxies Solar and Stellar Astrophysics Extensive rovibrational line lists are constructed for 12 isotopologues of carbon dioxide: $^{12}$C$^{16}$O$_2$, $^{13}$C$^{16}$O$_2$, $^{12}$C$^{17}$O$_2$, $^{13}$C$^{17}$O$_2$, $^{12}$C$^{18}$O$_2$, $^{13}$C$^{18}$O$_2$, $^{16}$O$^{12}$C$^{17}$O, $^{16}$O$^{12}$C$^{18}$O, $^{16}$O$^{13}$C$^{17}$O, $^{16}$O$^{13}$C$^{18}$O, $^{17}$O$^{12}$C$^{18}$O, and $^{17}$O$^{13}$C$^{18}$O. The variational program TROVE was employed together with an exact kinetic energy operator, accurate empirical potential energy surface (Ames-2) and the ab initio dipole moment surface Ames-2021-40K. Empirical energy levels from the most recent MARVEL analyses, as well as from the HITRAN and CDSD databases, are used to replace calculated values where available. The line lists are further supplemented by assigning AFGL quantum numbers using machine-learning based estimators. The resulting data were employed to generate opacities with four radiative transfer codes, TauREx, ARCiS, NEMESIS, and petitRADTRANS, both for individual isotopologues and for CO$_2$ at terrestrial isotopic natural abundance. All line lists and associated data are available at www.exomol.com. |
| title | ExoMol line lists -- LXIII: ExoMol line lists for 12 isotopologues of CO$_2$ |
| topic | Earth and Planetary Astrophysics Astrophysics of Galaxies Solar and Stellar Astrophysics |
| url | https://arxiv.org/abs/2512.13889 |