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Main Authors: Fujiyama, S., Ueda, K., Otsuka, Y.
Format: Preprint
Published: 2025
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Online Access:https://arxiv.org/abs/2512.16137
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author Fujiyama, S.
Ueda, K.
Otsuka, Y.
author_facet Fujiyama, S.
Ueda, K.
Otsuka, Y.
contents We present large-scale ab initio phonon calculations for the molecular quantum spin liquid X[Pd(dmit)2]2. An unusually low average phonon velocity ( 700 {m/s}) and optical modes below 10 cm^{-1} confine the Debye T^{3} regime to T < 2 K. As the transfer-integral anisotropy approaches the maximally frustrated regime (t'/t \to 1), the lattice stiffens, ruling out lattice softening as the origin of the spin-liquid state. By quantifying the additional suppression of the thermal conductivity from experimental data, we observe a power-law behavior consistent with two-dimensional magnetic excitations with a nodal, approximately linear (Dirac-like) spectrum.
format Preprint
id arxiv_https___arxiv_org_abs_2512_16137
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Power-Law Suppression of Phonon Thermal Transport by Magnetic Excitations in a Molecular Quantum Spin Liquid
Fujiyama, S.
Ueda, K.
Otsuka, Y.
Strongly Correlated Electrons
We present large-scale ab initio phonon calculations for the molecular quantum spin liquid X[Pd(dmit)2]2. An unusually low average phonon velocity ( 700 {m/s}) and optical modes below 10 cm^{-1} confine the Debye T^{3} regime to T < 2 K. As the transfer-integral anisotropy approaches the maximally frustrated regime (t'/t \to 1), the lattice stiffens, ruling out lattice softening as the origin of the spin-liquid state. By quantifying the additional suppression of the thermal conductivity from experimental data, we observe a power-law behavior consistent with two-dimensional magnetic excitations with a nodal, approximately linear (Dirac-like) spectrum.
title Power-Law Suppression of Phonon Thermal Transport by Magnetic Excitations in a Molecular Quantum Spin Liquid
topic Strongly Correlated Electrons
url https://arxiv.org/abs/2512.16137