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| Main Authors: | , |
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| Format: | Preprint |
| Published: |
2025
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| Subjects: | |
| Online Access: | https://arxiv.org/abs/2512.16173 |
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Table of Contents:
- Establishing symmetry-protected topological (SPT) phases with interactions in chemically realistic systems remains an open challenge. We show that a single, synthetically plausible organic one-dimensional chain, tunable via chemical modification of its radical sites, hosts two such phases: an odd-Haldane phase of a dimerized $S=\tfrac{1}{2}$ Heisenberg chain and a Haldane phase of an $S=1$ chain realized when Hund coupling locks two $S=\tfrac{1}{2}$ spins per monomer into $S=1$. Density-functional theory places the active manifold deep in the Mott regime ($U/t\!\approx\!126$), justifying a spin-only Heisenberg description; a compact $(t,U)\!\to\!J$ mapping then fixes exchange couplings. Exact diagonalization and DMRG reveal a consistent SPT fingerprint across both phases, including a quantized many-body Zak phase, even-degenerate entanglement spectrum, protected edge spins, and characteristic triplon/Haldane features in $S^{+-}(q,ω)$. Our results identify a chemically programmable molecular platform for interacting SPT physics in one dimension and suggest concrete spectroscopic routes to organic Haldane spin chains for nanoscale quantum devices.