Two-dimensional coherent spectroscopy of CoNb$_2$O$_6$

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Main Authors: Watanabe, Yoshito, Trebst, Simon, Hickey, Ciarán
Format: Preprint
Published: 2025
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author Watanabe, Yoshito
Trebst, Simon
Hickey, Ciarán
author_facet Watanabe, Yoshito
Trebst, Simon
Hickey, Ciarán
contents With recent advances in terahertz (THz) sources and detection, two-dimensional coherent spectroscopy (2DCS), which allows to probe nonlinear responses in a two-frequency plane, now reaches the meV regime relevant for quasiparticle excitations in magnetic materials. This opens a promising route to reveal many-body phenomena that evade linear-response probes. To date most experimental applications have focused on classical magnets, and a solid demonstration in a quantum magnet has yet to be established. Here we present a theoretical study of 2DCS in CoNb$_2$O$_6$, a quasi-one-dimensional Ising magnet that is believed to host fractionalized spinons which at low temperatures are confined by weak interchain coupling. Our analysis, which builds on an effective $S=1/2$ Hamiltonian is found to reveal unambiguous 2DCS signatures of spinon deconfinement above the low-temperature ordered phase. Using a four-spinon approximation, we track these 2DCS signatures by sequentially building a faithful microscopic model for CoNb$_2$O$_6$, starting from the exactly solvable one-dimensional transverse-field Ising model (1$d$ TFIM) and successively adding interactions to capture its key low-energy physics. In particular, adding a bond-dependent staggered YZ interaction to the 1$d$-TFIM already reproduces many key spectral features of the full material Hamiltonian. Within this TFIM+YZ model, we find a series of bound states, including a four-spinon bound state that is distinct from the familiar two-spinon bound states. We further find that introducing a confinement potential suppresses sharp spinon-echo features in the two-frequency space, which are thought to reflect an underlying continuum of fractionalized excitations. Our results provide concrete predictions and clear targets for future THz 2DCS experiments on CoNb$_2$O$_6$ and related quasi-one-dimensional quantum magnets.
format Preprint
id arxiv_https___arxiv_org_abs_2512_16829
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Two-dimensional coherent spectroscopy of CoNb$_2$O$_6$
Watanabe, Yoshito
Trebst, Simon
Hickey, Ciarán
Strongly Correlated Electrons
With recent advances in terahertz (THz) sources and detection, two-dimensional coherent spectroscopy (2DCS), which allows to probe nonlinear responses in a two-frequency plane, now reaches the meV regime relevant for quasiparticle excitations in magnetic materials. This opens a promising route to reveal many-body phenomena that evade linear-response probes. To date most experimental applications have focused on classical magnets, and a solid demonstration in a quantum magnet has yet to be established. Here we present a theoretical study of 2DCS in CoNb$_2$O$_6$, a quasi-one-dimensional Ising magnet that is believed to host fractionalized spinons which at low temperatures are confined by weak interchain coupling. Our analysis, which builds on an effective $S=1/2$ Hamiltonian is found to reveal unambiguous 2DCS signatures of spinon deconfinement above the low-temperature ordered phase. Using a four-spinon approximation, we track these 2DCS signatures by sequentially building a faithful microscopic model for CoNb$_2$O$_6$, starting from the exactly solvable one-dimensional transverse-field Ising model (1$d$ TFIM) and successively adding interactions to capture its key low-energy physics. In particular, adding a bond-dependent staggered YZ interaction to the 1$d$-TFIM already reproduces many key spectral features of the full material Hamiltonian. Within this TFIM+YZ model, we find a series of bound states, including a four-spinon bound state that is distinct from the familiar two-spinon bound states. We further find that introducing a confinement potential suppresses sharp spinon-echo features in the two-frequency space, which are thought to reflect an underlying continuum of fractionalized excitations. Our results provide concrete predictions and clear targets for future THz 2DCS experiments on CoNb$_2$O$_6$ and related quasi-one-dimensional quantum magnets.
title Two-dimensional coherent spectroscopy of CoNb$_2$O$_6$
topic Strongly Correlated Electrons
url https://arxiv.org/abs/2512.16829