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Hauptverfasser: Borel, A., Ivanova, T. V., Cervantes-Villanueva, J., Thor, P., Baek, H., Taniguchi, T., Watanabe, K., Molina-Sanchez, A., Gerardot, B. D., Brotons-Gisbert, M.
Format: Preprint
Veröffentlicht: 2025
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Online-Zugang:https://arxiv.org/abs/2512.21125
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author Borel, A.
Ivanova, T. V.
Cervantes-Villanueva, J.
Thor, P.
Baek, H.
Taniguchi, T.
Watanabe, K.
Molina-Sanchez, A.
Gerardot, B. D.
Brotons-Gisbert, M.
author_facet Borel, A.
Ivanova, T. V.
Cervantes-Villanueva, J.
Thor, P.
Baek, H.
Taniguchi, T.
Watanabe, K.
Molina-Sanchez, A.
Gerardot, B. D.
Brotons-Gisbert, M.
contents Moiré superlattices in transition-metal dichalcogenide semiconductor heterobilayers enable the quantum confinement of interlayer excitons with large out-of-plane permanent electric dipoles and spin-valley control. Here, we report a novel phonon-assisted excitation mechanism of individual moiré-trapped interlayer excitons in 2H-stacked MoSe$_2$/WSe$_2$ heterobilayers via chiral $E^{\prime\prime}$ in-plane optical phonons at the Γ-point. This excitation pathway preserves valley-selective optical selection rules and enables deterministic generation of individual interlayer excitons with defined helicity, emitting within a spectrally narrow energy spread. Through photoluminescence excitation spectroscopy in both the ensemble and quantum emitter regimes, we identify a fixed phonon energy of $\sim$23 meV mediating the process. First-principles calculations corroborate the symmetry and energy of the relevant phonon mode and its coupling to interlayer excitons, providing microscopic support for the observed valley-selective phonon-assisted excitation mechanism. Our results highlight the utility of chiral phonons as a tool for controlled excitation of quantum emitters in TMD moiré systems, opening new opportunities for valleytronic and quantum photonic applications.
format Preprint
id arxiv_https___arxiv_org_abs_2512_21125
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Photoexcitation of moiré-trapped interlayer excitons via chiral phonons
Borel, A.
Ivanova, T. V.
Cervantes-Villanueva, J.
Thor, P.
Baek, H.
Taniguchi, T.
Watanabe, K.
Molina-Sanchez, A.
Gerardot, B. D.
Brotons-Gisbert, M.
Quantum Physics
Materials Science
Moiré superlattices in transition-metal dichalcogenide semiconductor heterobilayers enable the quantum confinement of interlayer excitons with large out-of-plane permanent electric dipoles and spin-valley control. Here, we report a novel phonon-assisted excitation mechanism of individual moiré-trapped interlayer excitons in 2H-stacked MoSe$_2$/WSe$_2$ heterobilayers via chiral $E^{\prime\prime}$ in-plane optical phonons at the Γ-point. This excitation pathway preserves valley-selective optical selection rules and enables deterministic generation of individual interlayer excitons with defined helicity, emitting within a spectrally narrow energy spread. Through photoluminescence excitation spectroscopy in both the ensemble and quantum emitter regimes, we identify a fixed phonon energy of $\sim$23 meV mediating the process. First-principles calculations corroborate the symmetry and energy of the relevant phonon mode and its coupling to interlayer excitons, providing microscopic support for the observed valley-selective phonon-assisted excitation mechanism. Our results highlight the utility of chiral phonons as a tool for controlled excitation of quantum emitters in TMD moiré systems, opening new opportunities for valleytronic and quantum photonic applications.
title Photoexcitation of moiré-trapped interlayer excitons via chiral phonons
topic Quantum Physics
Materials Science
url https://arxiv.org/abs/2512.21125