Variation on the theme of Jarzynski's inequality

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Hauptverfasser: Castellanos, Dani R., Jizba, Petr
Format: Preprint
Veröffentlicht: 2026
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author Castellanos, Dani R.
Jizba, Petr
author_facet Castellanos, Dani R.
Jizba, Petr
contents The Jarzynski equality, which relates equilibrium free-energy difference to an average of non-equilibrium work, plays a central role in modern non-equilibrium statistical thermodynamics. In this paper, we study a weaker consequence of this relation, known as Jarzynski's inequality, which can be formally obtained from the Jarzynski equality via Jensen's inequality. We identify and analyze several extensions of Jarzynski's inequality that go beyond its direct derivation from the Jarzynski equality. In particular, we consider chemical systems both in the linear-response regime and away from linear thermodynamics. Furthermore, by employing functional-integral techniques, we extend Jarzynski's inequality to many-body statistical systems described by quantum field theory. Salient issues, such as connections of the Jarzynski inequality with the maximum work theorem and the Landau--Lifshitz theory of fluctuations, are also discussed.
format Preprint
id arxiv_https___arxiv_org_abs_2601_01644
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Variation on the theme of Jarzynski's inequality
Castellanos, Dani R.
Jizba, Petr
Statistical Mechanics
Chemical Physics
Quantum Physics
The Jarzynski equality, which relates equilibrium free-energy difference to an average of non-equilibrium work, plays a central role in modern non-equilibrium statistical thermodynamics. In this paper, we study a weaker consequence of this relation, known as Jarzynski's inequality, which can be formally obtained from the Jarzynski equality via Jensen's inequality. We identify and analyze several extensions of Jarzynski's inequality that go beyond its direct derivation from the Jarzynski equality. In particular, we consider chemical systems both in the linear-response regime and away from linear thermodynamics. Furthermore, by employing functional-integral techniques, we extend Jarzynski's inequality to many-body statistical systems described by quantum field theory. Salient issues, such as connections of the Jarzynski inequality with the maximum work theorem and the Landau--Lifshitz theory of fluctuations, are also discussed.
title Variation on the theme of Jarzynski's inequality
topic Statistical Mechanics
Chemical Physics
Quantum Physics
url https://arxiv.org/abs/2601.01644