Gespeichert in:
| Hauptverfasser: | , |
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| Format: | Preprint |
| Veröffentlicht: |
2026
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| Schlagworte: | |
| Online-Zugang: | https://arxiv.org/abs/2601.01776 |
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Inhaltsangabe:
- Superspreading wetting is traditionally attributed to surfactant-driven mechanisms. However, recent observations of superspreading in surfactant-free nanofluids defy standard theoretical explanations. This study considers a data-driven approach to model droplet dynamics with the thickness of liquid films on the nanometer-micrometer scale in a compact form of a partial differential equation. We examine spatiotemporal film-thickness profiles resolved at the nanometer scale via phase-shifting imaging ellipsometry. For a pure solvent, the present governing equation recovers the classical lubrication physics driven by disjoining pressure and evaporation. In contrast, the nanofluid dynamics necessitates a unique transport term scaling with the gradient of the inverse film thickness. Theoretical analysis suggests this term represents a nanoparticle-induced bias flux, consistent with a hypothesized capillary wicking mechanism within the precursor film. The identification of the current nanofluid-specific term underscores the efficacy of integrating high-precision experimental measurements with data-driven modeling to unravel complex wetting dynamics.