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Main Authors: Fischetti, Alessia, Mineo, Giacometta, Russo, Daniela, Salutari, Francesco, Campallegio, Claudio Lentini, Bruno, Elena, Arbiol, Jordi, Franzò, Giorgia, Mirabella, Salvatore, Strano, Vincenzina, Spadaro, M. Chiara
Format: Preprint
Published: 2026
Subjects:
Online Access:https://arxiv.org/abs/2601.06509
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author Fischetti, Alessia
Mineo, Giacometta
Russo, Daniela
Salutari, Francesco
Campallegio, Claudio Lentini
Bruno, Elena
Arbiol, Jordi
Franzò, Giorgia
Mirabella, Salvatore
Strano, Vincenzina
Spadaro, M. Chiara
author_facet Fischetti, Alessia
Mineo, Giacometta
Russo, Daniela
Salutari, Francesco
Campallegio, Claudio Lentini
Bruno, Elena
Arbiol, Jordi
Franzò, Giorgia
Mirabella, Salvatore
Strano, Vincenzina
Spadaro, M. Chiara
contents Low-cost and environmentally friendly electrochemical energy storage systems are crucial to address the increasing global energy demand. Nanomaterials can play a pivotal role in catalysing charge storage and/or exchange, still the underlying mechanism often remains poorly investigated, as for ZnO/ZnS nanostructures onto Ni foam. In this work, we investigate hydrothermally grown ZnO/ZnS nanostructures decorating Ni foam for energy storage application. Morphology, structure and composition are evaluated via electron microscopy-based methodologies. The electrochemical energy storage performance is evaluated by cyclic voltammetry (CV) measurements with the aim to highlight the energy storage mechanism. When nickel foam (NF) is used as substrate, the system shows a predominant pseudocapacitive behaviour. By contrast, a modest and capacitive performance is measured on graphene paper (GP). Mott-Schottky (M-S) and open circuit potential (OCP) measurements suggests a key role of hole reservoir in ZnS decoration which boosts NF performances.
format Preprint
id arxiv_https___arxiv_org_abs_2601_06509
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle ZnO/ZnS heterostructures as hole reservoir to boost Ni foam energy storage performance
Fischetti, Alessia
Mineo, Giacometta
Russo, Daniela
Salutari, Francesco
Campallegio, Claudio Lentini
Bruno, Elena
Arbiol, Jordi
Franzò, Giorgia
Mirabella, Salvatore
Strano, Vincenzina
Spadaro, M. Chiara
Materials Science
Low-cost and environmentally friendly electrochemical energy storage systems are crucial to address the increasing global energy demand. Nanomaterials can play a pivotal role in catalysing charge storage and/or exchange, still the underlying mechanism often remains poorly investigated, as for ZnO/ZnS nanostructures onto Ni foam. In this work, we investigate hydrothermally grown ZnO/ZnS nanostructures decorating Ni foam for energy storage application. Morphology, structure and composition are evaluated via electron microscopy-based methodologies. The electrochemical energy storage performance is evaluated by cyclic voltammetry (CV) measurements with the aim to highlight the energy storage mechanism. When nickel foam (NF) is used as substrate, the system shows a predominant pseudocapacitive behaviour. By contrast, a modest and capacitive performance is measured on graphene paper (GP). Mott-Schottky (M-S) and open circuit potential (OCP) measurements suggests a key role of hole reservoir in ZnS decoration which boosts NF performances.
title ZnO/ZnS heterostructures as hole reservoir to boost Ni foam energy storage performance
topic Materials Science
url https://arxiv.org/abs/2601.06509