Giant Hole-doping in 2H-WSe2 via Ta Substitution

Fuente: arXiv
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Autori principali: Kang, Minhee, Choi, Woojin, Hwang, Choongyu, Hwang, Jinwoong
Natura: Preprint
Pubblicazione: 2026
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author Kang, Minhee
Choi, Woojin
Hwang, Choongyu
Hwang, Jinwoong
author_facet Kang, Minhee
Choi, Woojin
Hwang, Choongyu
Hwang, Jinwoong
contents The family of transition metal dichalcogenides (TMDCs) has been regarded as promising candidates for future electronics, valleytronics, spintronics, and optoelectronics. While most of TMDCs are intrinsic n-type semiconductors due to electron donation from chalcogen vacancies, realizing intrinsic p-type TMDCs and achieving precise control over their electronic properties remain challenging. In this work, we introduce a powerful approach to obtain intrinsic hole doping by substituting Ta atom into 2H-WSe2. A combining study of molecular beam epitaxy growth and in-situ angle-resolved photoemission spectroscopy characterization clearly reveals that Ta substitution induces a significant hole doping and provides a possible way of a semiconductor-to-metal transition in 2H-WSe2.
format Preprint
id arxiv_https___arxiv_org_abs_2601_08284
institution arXiv
publishDate 2026
record_format arxiv
spellingShingle Giant Hole-doping in 2H-WSe2 via Ta Substitution
Kang, Minhee
Choi, Woojin
Hwang, Choongyu
Hwang, Jinwoong
Materials Science
The family of transition metal dichalcogenides (TMDCs) has been regarded as promising candidates for future electronics, valleytronics, spintronics, and optoelectronics. While most of TMDCs are intrinsic n-type semiconductors due to electron donation from chalcogen vacancies, realizing intrinsic p-type TMDCs and achieving precise control over their electronic properties remain challenging. In this work, we introduce a powerful approach to obtain intrinsic hole doping by substituting Ta atom into 2H-WSe2. A combining study of molecular beam epitaxy growth and in-situ angle-resolved photoemission spectroscopy characterization clearly reveals that Ta substitution induces a significant hole doping and provides a possible way of a semiconductor-to-metal transition in 2H-WSe2.
title Giant Hole-doping in 2H-WSe2 via Ta Substitution
topic Materials Science
url https://arxiv.org/abs/2601.08284